A Luminescent Material: La3Cl(CN2)O3 Doped with Eu3+ or Tb3+ Ions

被引：8
作者：
Kubus, Mariusz [1 ]
Enseling, David [2 ]
Juestel, Thomas [2 ]
Meyer, H-Juergen [1 ]
机构：
[1] Univ Tubingen, Inst Anorgan Chem, Abt Festkorperchem & Theoret Anorgan Chem, D-72076 Tubingen, Germany
[2] Fachhsch Munster, Lab Angew Mat Wissensch, D-48565 Steinfurt, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 18期
关键词：
Carbodiimide; Oxido ligands; Luminescence; Metathesis; STATE METATHESIS REACTIONS; RARE-EARTH DIOXYMONOCYANAMIDES; CRYSTAL-STRUCTURE; CARBODIIMIDES; CYANAMIDE; COMPOUND; LA2O2CN2; PR; LN;
D O I：
10.1002/ejic.201300224
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new carbodiimide compound La3Cl(CN2)O3 was obtained by a solid-state metathesis reaction from LaOCl and Li2(CN2) at 750 degrees C in a fused tube. Differential scanning calorimetry of the reaction mixture was performed. The crystal structure of La3Cl(CN2)O3 was determined by single-crystal X-ray diffraction studies (space group Cmcm, No. 63). The luminescent properties of the Eu3+- and Tb3+-doped compounds are reported.
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收藏
页码：3195 / 3199
页数：5
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