Preparation and electrochemical performances of doped MXene/poly (3,4-ethylenedioxythiophene) composites

被引：43

作者：

Chen, Zhongxing ^{[1
]}

Han, Yongqin ^{[1
]}

Li, Tingxi ^{[1
]}

Zhang, Xingwei ^{[1
]}

Wang, Tianqi ^{[1
]}

Zhang, Zonglin ^{[1
]}

机构：

[1] Shandong Univ Sci & Technol, Dept Polymer Mat, Coll Mat Sci & Engn, Qingdao 266510, Peoples R China

来源：

MATERIALS LETTERS | 2018年 / 220卷

基金：

中国国家自然科学基金;

关键词：

MXene; Poly(3,4-ethylenedioxythiophene); Nanocomposites; Microstructure; Electrochemical performance; ELECTRODES;

D O I：

10.1016/j.matlet.2018.03.049

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Mono- and co-doped MXene(Ti3C2Tx)/poly(3,4-ethylenedioxythiophene)(PEDOT) composites (MPTs) are prepared by in situ chemical method. The obtained co-doped-MPTs electrode materials with lamellar composite microstructure, which could facilitate the transmission of electrons and ions, provide improved electrochemical performances. The potential window of the doped MPTs can be enlarged to 1.8 V. Compared with 1,5-naphathalene disulfonic acid/H3PMo12O40 co-doped MPTs, 1,5-naphathalene disulfonic acid/anthraquinone-2-sulfonate (AQS) co-doped MPTs can provide higher specific capacitance of 323 F/g (more than two times as much as that of pristine MXene and PEDOT) and ideal capacitive behavior, which could be attributed to the co-doping effect as well as the Faradaic reaction of AQS. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：305 / 308

页数：4

共 13 条

[1] Pseudocapacitive Electrodes Produced by Oxidant-Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene) [J].

Boota, Muhammad ;

Anasori, Babak ;

Voigt, Cooper ;

Zhao, Meng-Qiang ;

Barsoum, Michel W. ;

Gogotsi, Yury .

ADVANCED MATERIALS, 2016, 28 (07) :1517-1522

[2] The role of water in the synthesis and performance of vapour phase polymerised PEDOT electrochromic devices [J].

Fabretto, Manrico ;

Zuber, Kamil ;

Hall, Colin ;

Murphy, Peter ;

Griesser, Hans J. .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (42) :7871-7878

[3] In situ spectroelectrochemical Raman studies of poly(3,4-ethylenedioxythiophene) (PEDT) [J].

Garreau, S ;

Louarn, G ;

Buisson, JP ;

Froyer, G ;

Lefrant, S .

MACROMOLECULES, 1999, 32 (20) :6807-6812

[4] Ultrathin Nickel-Cobalt Phosphate 2D Nanosheets for Electrochemical Energy Storage under Aqueous/Solid-State Electrolyte [J].

Li, Bing ;

Gu, Peng ;

Feng, Yongcheng ;

Zhang, Guangxun ;

Huang, Kesheng ;

Xue, Huaiguo ;

Pang, Huan .

ADVANCED FUNCTIONAL MATERIALS, 2017, 27 (12)

[5] Syntheses and Energy Storage Applications of MxSy (M = Cu, Ag, Au) and Their Composites: Rechargeable Batteries and Supercapacitors [J].

Lu, Yao ;

Li, Bing ;

Zheng, Shasha ;

Xu, Yuxia ;

Xue, Huaiguo ;

Pang, Huan .

ADVANCED FUNCTIONAL MATERIALS, 2017, 27 (44)

[6] 25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials [J].

Naguib, Michael ;

Mochalin, Vadym N. ;

Barsoum, Michel W. ;

Gogotsi, Yury .

ADVANCED MATERIALS, 2014, 26 (07) :992-1005

[7] Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2 [J].

Naguib, Michael ;

Kurtoglu, Murat ;

Presser, Volker ;

Lu, Jun ;

Niu, Junjie ;

Heon, Min ;

Hultman, Lars ;

Gogotsi, Yury ;

Barsoum, Michel W. .

ADVANCED MATERIALS, 2011, 23 (37) :4248-4253

[8] Effect of Postetch Annealing Gas Composition on the Structural and Electrochemical Properties of Ti2CTx MXene Electrodes for Supercapacitor Applications [J].

Rakhi, R. B. ;

Ahmed, Bilal ;

Hedhili, M. N. ;

Anjum, Dalaver H. ;

Alshareef, H. N. .

CHEMISTRY OF MATERIALS, 2015, 27 (15) :5314-5323

[9] Direct Chemical Synthesis of MnO2 Nanowhiskers on Transition Metal Carbide Surfaces for Supercapacitor Applications [J].

Rakhi, Raghavan Baby ;

Ahmed, Bilal ;

Anjum, Dalaver ;

Alshareef, Husam N. .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (29) :18806-18814

[10] Continental flood basalts derived from the hydrous mantle transition zone [J].

Wang, Xuan-Ce ;

Wilde, Simon A. ;

Li, Qiu-Li ;

Yang, Ya-Nan .

NATURE COMMUNICATIONS, 2015, 6

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