Unidirectional Charge Transfer in Di-cobalt Valence Tautomeric Compound Finely Tuned by Ancillary Ligand

被引:18
作者
Li, Bao [1 ,2 ,3 ]
Chen, Li-Qin [1 ,2 ]
Tao, Jun [1 ,2 ]
Huang, Rong-Bin [1 ,2 ]
Zheng, Lan-Sun [1 ,2 ]
机构
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[2] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
[3] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China
关键词
TRANSITION-METAL COMPLEXES; ELECTRON-TRANSFER; MAGNETIC-PROPERTIES; TETRAOXOLENE COMPLEX; THERMAL HYSTERESIS; SPIN-TRANSITION; CATECHOLATE; BISTABILITY; TEMPERATURE; SEMIQUINONE;
D O I
10.1021/ic4000268
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A dinuclear valence tautomeric compound containing a cationic structure with crystallographically distinguishable hs-Co-II and ls-Co-III centers undergoes unidirectional charge transfer.
引用
收藏
页码:4136 / 4138
页数:3
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