Supramolecular polymers at work

被引：227
作者：
Bosman, Anton W. [1 ]
Sijbesma, Rint P. [2 ]
Meijer, E. W. [2 ]
机构：
[1] SupraPolix Res Ctr, NL-5612 AX Eindhoven, Netherlands
[2] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5300 MB Eindhoven, Netherlands
来源：
MATERIALS TODAY | 2004年 / 7卷 / 04期
关键词：
D O I：
10.1016/S1369-7021(04)00187-7
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Sophisticated polymeric materials with 'responsive' properties are beginning to reach the market. The use of reversible, noncovalent interactions is a recurring design principle for responsive materials. Now, recently developed hydrogen-bonding units allow this design principle to be taken to its extreme. Supramolecular polymers, where hydrogen bonds are the only force keeping the monomers together, form materials whose (mechanical) properties respond strongly to a change in temperature or solvent. In this review, we describe the developments that have led to hydrogen-bonded supramolecular polymers and discuss the use of these materials in advanced applications. © 2004 Elsevier Ltd.
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页码：34 / 39
页数：6
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