Amberlite IRA900F as a solid fluoride source for a variety of organic transformations under solvent-free conditions

被引：36

作者：

Fringuelli, Francesco ^{[1
]}

Lanari, Daniela ^{[1
]}

Pizzo, Ferdinando ^{[1
]}

Vaccaro, Luigi ^{[1
]}

机构：

[1] Univ Perugia, Dipartimento Chim, Lab Green Synthet Organ Chem, I-06123 Perugia, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 2008卷 / 23期

关键词：

supported catalysts; green chemistry; nitro compounds;

D O I：

10.1002/ejoc.200800142

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have reported that Amberlite IRA900F (Amb-F) is an efficient metal-free catalyst for the activation of Si-N and Si-O bonds and a mild base in a variety of organic transformations under solvent-free conditions, such as the addition of TMSN3 to (E)-2-aryl-1-cyano-1-nitroethenes, nitriles, alpha,beta-unsaturated acids and their esters, and the addition of dimethylsilyl ketene acetal and ethyl nitroacetate to beta-nitro styrenes. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

引用

页码：3928 / 3932

页数：5

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