Synthesis, structures, and properties of lead(II) and cobalt(II) metal-organic frameworks based on a flexible benzophenone-2,4′-dicarboxylic acid (H2bpdc)

被引：6
作者：
Chen, Peng-Xiang [1 ]
Yang, Guo-Ping [1 ]
Hou, Lei [1 ]
Wang, Yao-Yu [1 ]
Shi, Qi-Zhen [1 ]
机构：
[1] NW Univ Xian, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ,Shaanxi Key Lab Phys Inorgan Chem, Xian 710069, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 16期
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Hydrogen bonding; pi center dot center dot center dot pi Stacking; Fluorescence; Luminescent lifetime; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SUPRAMOLECULAR STRUCTURE; MAGNETIC-PROPERTIES; CHAINS; COMPLEXES; NETWORKS; LIGAND; ARCHITECTURES; RECOGNITION;
D O I：
10.1080/00958972.2012.704025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new coordination polymers, [Pb(bpdc)](n) (1) and [Co(bpdc)(phen)](n) (2) [H(2)bpdc = benzophenone-2,4'-dicarboxylic acid, phen = 1,10-phenanthroline], have been synthesized and structurally characterized. Hydrogen bonding and pi center dot center dot center dot pi stacking extend 1 and 2 into 3-D supramolecular architectures, where 1 exhibits a 3-D framework with 1-D hairpin-like helicates based on Pb-O covalent bonds and 2 displays a 3-D network with 1-D zipper-like chains based on Co-O and Co-N covalent bonds. The FT-IR spectra, PXRD and TG analyses are discussed for 1 and 2. Fluorescence spectra and luminescent lifetime are studied for 1.
引用
收藏
页码：2893 / 2902
页数：10
相关论文
共 50 条
  • [21] Series of Cd(II) Metal-Organic Frameworks Based on a Flexible Tripodal Ligand and Polycarboxylate Acids: Syntheses, Structures, and Photoluminescent Properties
    Wang, Xianjuan
    Liu, Yanhua
    Xu, Chunying
    Guo, Qianqian
    Hou, Hongwei
    Fan, Yaoting
    CRYSTAL GROWTH & DESIGN, 2012, 12 (05) : 2435 - 2444
  • [22] A new strategy to obtain tetranuclear cobalt(II) metal-organic frameworks based on the [Co4(μ3-OH)2] cluster: synthesis, structures and properties
    Li, Ke
    Lv, Xiu-Xiu
    Shi, Lu-Lu
    Liu, Lu
    Li, Bao-Long
    Wu, Bing
    DALTON TRANSACTIONS, 2016, 45 (38) : 15078 - 15088
  • [23] Flexible Co(II)-and Ni(II)-Based Cationic 2D Metal-Organic Frameworks Based on a Charge-Neutral (O,O)-Donor Bridge
    Demakov, Pavel A.
    Kovalenko, Konstantin A.
    Lavrov, Alexander N.
    Fedin, Vladimir P.
    INORGANICS, 2023, 11 (06)
  • [24] Synthesis, crystal structure and photophysical studies on a ruthenium(II) carbonyl hydrido compound based on 2,2′-bipyridyl-5,5′-dicarboxylic acid (H2bpdc)
    Xiang, Jing
    Li, Zai-Gao
    Zou, Hua
    CRYSTAL RESEARCH AND TECHNOLOGY, 2013, 48 (02) : 87 - 93
  • [25] Two new zinc(II) metal-organic frameworks based on 1,4-bis (2-methyl-imidazol-1-yl)butane: synthesis, structures, and properties
    Jin, Jun-Cheng
    Tong, Wen-Quan
    Xie, Cheng-Gen
    Chang, Wen-Gui
    Xu, Guang-Nian
    Wu, Ju
    Li, Lin-Gang
    Yan, Zheng-Quan
    Wang, Yao-Yu
    JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (21) : 3697 - 3705
  • [26] Four novel Zn(II)/Cd(II) metal-organic frameworks constructed from 4′-(4-pyridyl)-4,2′:6′,4"-terpyridine: hydrothermal synthesis, crystal structures, and luminescent properties
    Wang, Bao-Cheng
    Wu, Qing-Ran
    Hu, Huai-Ming
    Chen, Xiao-Li
    Yang, Zhen-Hua
    Shangguan, Yi-Qing
    Yang, Meng-Lin
    Xue, Gang-Lin
    CRYSTENGCOMM, 2010, 12 (02): : 485 - 492
  • [27] Hydrothermal Synthesis, Structures, and Luminescent Properties of Seven d10 Metal-Organic Frameworks Based on 9,9-Dipropylfluorene-2,7-Dicarboxylic Acid (H2DFDA)
    Guo, Hua-Dong
    Guo, Xian-Min
    Batten, Stuart R.
    Song, Jiang-Feng
    Song, Shu-Yan
    Dang, Song
    Zheng, Guo-Li
    Tang, Jin-Kui
    Zhang, Hong-Jie
    CRYSTAL GROWTH & DESIGN, 2009, 9 (03) : 1394 - 1401
  • [28] Zinc(II) and Copper(II) Metal-Organic Frameworks Constructed from a Terphenyl-4,4''-dicarboxylic Acid Derivative: Synthesis, Structure, and Catalytic Application in the Cyanosilylation of Aldehydes
    Karmakar, Anirban
    Paul, Anup
    Rubio, Guilherme M. D. M.
    Guedes da Silva, M. Fatima C.
    Pombeiro, Armando J. L.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (36) : 5557 - 5567
  • [29] Ni(II)-metal-organic frameworks based on 1,4-phenylenedipropionic acid: Solvothermal syntheses, structures, and photocatalytic properties
    Sanram, Surapoj
    Boonmak, Jaursup
    Youngme, Sujittra
    POLYHEDRON, 2016, 119 : 151 - 159
  • [30] Metal-Organic Frameworks of Cobalt(II) with 4,7-Di(1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole and Aromatic Dicarboxylic Acids: Synthesis, Crystal Structures, and Magnetic Properties
    Pavlov, D. I.
    Lavrov, A. N.
    Samsonenko, D. G.
    Potapov, A. S.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2024, 50 (09) : 673 - 682
12345