Getting more from pushing less: Negative specific heat and conductivity in nonequilibrium steady states

被引:74
作者
Zia, RKP [1 ]
Praestgaard, EL
Mouritsen, OG
机构
[1] Virginia Polytech Inst & State Univ, Ctr Stochast Proc Sci & Engn, Blacksburg, VA 24061 USA
[2] Virginia Polytech Inst & State Univ, Dept Phys, Blacksburg, VA 24061 USA
[3] Univ Essen Gesamthsch, Fachbereich Phys, D-45117 Essen, Germany
[4] Roskilde Univ, Dept Chem & Life Sci, DK-4000 Roskilde, Denmark
[5] Univ So Denmark Odense, Dept Phys, DK-5230 Odense, Denmark
关键词
D O I
10.1119/1.1427088
中图分类号
G40 [教育学];
学科分类号
040101 ; 120403 ;
摘要
For students familiar with equilibrium statistical mechanics, the notion of a positive specific heat, being intimately related to the idea of stability, is both intuitively reasonable and mathematically provable. However, for systems in nonequilibrium stationary states, coupled to more than one energy reservoir, a negative specific heat is entirely possible. We present a minimal system that displays this phenomenon. For a system in contact with two thermal baths at different temperatures, the (internal) energy may increase when a thermostat is turned down. In another context, a similar phenomenon is negative conductivity, where a current may increase by decreasing the drive (for example, an external electric field). The counter-intuitive behavior in both processes may be described as getting more from pushing less. The crucial ingredients for this phenomenon and the elements needed for a minimal system are also presented. (C) 2002 American Association of Physics. Teachers.
引用
收藏
页码:384 / 392
页数:9
相关论文
共 16 条
  • [1] Eddington A.S., 1926, INTERNAL CONSTITUTIO
  • [2] Eddington AS, 1916, MON NOT R ASTRON SOC, V77, P0596
  • [3] LONG-RANGE CORRELATIONS FOR CONSERVATIVE DYNAMICS
    GARRIDO, PL
    LEBOWITZ, JL
    MAES, C
    SPOHN, H
    [J]. PHYSICAL REVIEW A, 1990, 42 (04): : 1954 - 1968
  • [4] Phase transitions and steady-state microstructures in a two-temperature lattice-gas model with mobile active impurities
    Henriksen, JR
    Sabra, MC
    Mouritsen, OG
    [J]. PHYSICAL REVIEW E, 2000, 62 (05): : 7070 - 7076
  • [5] NONEQUILIBRIUM STEADY-STATES OF STOCHASTIC LATTICE GAS MODELS OF FAST IONIC CONDUCTORS
    KATZ, S
    LEBOWITZ, JL
    SPOHN, H
    [J]. JOURNAL OF STATISTICAL PHYSICS, 1984, 34 (3-4) : 497 - 537
  • [6] PHASE-TRANSITIONS IN STATIONARY NON-EQUILIBRIUM STATES OF MODEL LATTICE SYSTEMS
    KATZ, S
    LEBOWITZ, JL
    SPOHN, H
    [J]. PHYSICAL REVIEW B, 1983, 28 (03): : 1655 - 1658
  • [7] KAWASAKI K, 1972, PHASE TRANSITIONS CR, V2
  • [8] Negative specific heat in astronomy, physics and chemistry
    Lynden-Bell, D
    [J]. PHYSICA A, 1999, 263 (1-4): : 293 - 304
  • [9] EQUATION OF STATE CALCULATIONS BY FAST COMPUTING MACHINES
    METROPOLIS, N
    ROSENBLUTH, AW
    ROSENBLUTH, MN
    TELLER, AH
    TELLER, E
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (06) : 1087 - 1092
  • [10] MUKAMEL D, 2000, SOFT FRAGILE MATTER