First example of a dumbbell-like architecture containing M3L2 cages and terephthalate anions

被引：71
作者：
Fan, J
Sun, WY [1 ]
Okamura, T
Xie, J
Tang, WX
Ueyama, N
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan
来源：
NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 02期
关键词：
D O I：
10.1039/b109141g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel complex [Ag-3(titmb)(2)](2)[1,4-C6H4(COO)(2)](3).23 H2O [titmb = 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene] contains two M3L2 cages and three terephthalate anions, one of which is embedded in the two cages to form a dumbbell-like architecture and shows photoluminescence in the solid state when the titmb reacts with [Ag(NH3)(2)]NO3, an individual M3L2 cage [Ag-3(titmb)(2)][NO3](3).5 H2O without luminescent properties was obtained.
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收藏
页码：199 / 201
页数：3
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