Production and upgrading of 5-hydroxymethylfurfural using heterogeneous catalysts and biomass-derived solvents

被引：305

作者：

Gallo, Jean Marcel R. ^{[1
]}

Alonso, David Martin ^{[1
]}

Mellmer, Max A. ^{[1
]}

Dumesic, James A. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA

来源：

GREEN CHEMISTRY | 2013年 / 15卷 / 01期

基金：

美国国家科学基金会;

关键词：

SOLID ACID CATALYSTS; GAMMA-VALEROLACTONE; D-FRUCTOSE; GLUCOSE; DEHYDRATION; ISOMERIZATION; MECHANISM; FUELS; WATER; OXIDATION;

D O I：

10.1039/c2gc36536g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High yields of HMF from glucose can be achieved using biomass-derived solvents and a combination of solid Lewis and Bronsted catalysts in a salt-free reaction system. The HMF produced in this system can be oxidized to FDCA or hydrogenated to DMF, both being high-value chemicals.

引用

页码：85 / 90

页数：6

共 38 条

[1] Catalytic conversion of biomass to biofuels [J].

Alonso, David Martin ;

Bond, Jesse Q. ;

Dumesic, James A. .

GREEN CHEMISTRY, 2010, 12 (09) :1493-1513

[2] Mechanism of the dehydration of D-fructose to 5-hydroxymethylfurfural in dimethyl sulfoxide at 150 °C: an NMR study [J].

Amarasekara, Ananda S. ;

Williams, LaToya D. ;

Ebede, Chidinma C. .

CARBOHYDRATE RESEARCH, 2008, 343 (18) :3021-3024

[3]

[Anonymous], 2011, Eurasian Chemical Market International Magazine, V8, P56

[4] KINETIC-STUDIES OF THE REACTIONS OF KETOSES AND ALDOSES IN WATER AT HIGH-TEMPERATURE .1. MECHANISM OF FORMATION OF 5-(HYDROXYMETHYL)-2-FURALDEHYDE FROM D-FRUCTOSE AND SUCROSE [J].

ANTAL, MJ ;

MOK, WSL ;

RICHARDS, GN .

CARBOHYDRATE RESEARCH, 1990, 199 (01) :91-109

[5] Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals [J].

Binder, Joseph B. ;

Raines, Ronald T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1979-1985

[6] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[7] Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing [J].

Carlos Serrano-Ruiz, Juan ;

Luque, Rafael ;

Sepulveda-Escribano, Antonio .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (11) :5266-5281

[8] CHEMICAL INTERMEDIATES FROM FURFURAL [J].

CASS, OW .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1948, 40 (02) :216-219

[9] Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides [J].

Chheda, Juben N. ;

Roman-Leshkov, Yuriy ;

Dumesic, James A. .

GREEN CHEMISTRY, 2007, 9 (04) :342-350

[10] Add-Functionalized SBA-15-Type Silica Catalysts for Carbohydrate Dehydration [J].

Crisci, Anthony J. ;

Tucker, Mark H. ;

Lee, Ming-Yung ;

Jang, Se Gyu ;

Dumesic, James A. ;

Scott, Susannah L. .

ACS CATALYSIS, 2011, 1 (07) :719-728

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