Effect of co-intercalated organic solvents in graphite on electrochemical Li intercalation

被引：22

作者：

Abe, T ^{[1
]}

Mizutani, Y

Kawabata, N

Inaba, M

Ogumi, Z

机构：

[1] Kyoto Univ, Grad Sch Engn, Sakyo Ku, Kyoto 6068501, Japan

[2] Kyoto Univ, Inst Adv Energy, Sakyo Ku, Uji, Kyoto 6100011, Japan

来源：

SYNTHETIC METALS | 2001年 / 125卷 / 02期

基金：

日本学术振兴会;

关键词：

co-intercalation; lithium intercalation; graphite;

D O I：

10.1016/S0379-6779(01)00538-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrochemical properties of graphite in propylene carbonate based electrolytes containing various organic solvents have been studied by cyclic voltammetry and charge-discharge measurements. Good correlation between solvent co-intercalation and electrochemical lithium intercalation into graphite was found. Effect of co-intercalated organic solvents in graphite on electrochemical Li intercalation was discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：249 / 253

页数：5

共 23 条

[1] Intercalation of lithium into natural graphite flakes and heat-treated polyimide films in ether-type solvents by chemical method [J].

Abe, T ;

Mizutani, Y ;

Tabuchi, T ;

Ikeda, K ;

Asano, M ;

Harada, T ;

Inaba, M ;

Ogumi, Z .

JOURNAL OF POWER SOURCES, 1997, 68 (02) :216-220

[2]

ABE T, UNPUB J ELECTROCHEM

[3]

AUBACH D, 1995, J ELECTROCHEM SOC, V142, P1746

[4] Failure and stabilization mechanisms of graphite electrodes [J].

Aurbach, D ;

Levi, MD ;

Levi, E ;

Schechter, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (12) :2195-2206

[5] FILMING MECHANISM OF LITHIUM-CARBON ANODES IN ORGANIC AND INORGANIC ELECTROLYTES [J].

BESENHARD, JO ;

WINTER, M ;

YANG, J ;

BIBERACHER, W .

JOURNAL OF POWER SOURCES, 1995, 54 (02) :228-231

[6] Origin of graphite exfoliation - An investigation of the important role of solvent cointercalation [J].

Chung, GC ;

Kim, HJ ;

Yu, SI ;

Jun, SH ;

Choi, JW ;

Kim, MH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (12) :4391-4398

[7] SUPPRESSION OF STAGING IN LITHIUM-INTERCALATED CARBON BY DISORDER IN THE HOST [J].

DAHN, JR ;

FONG, R ;

SPOON, MJ .

PHYSICAL REVIEW B, 1990, 42 (10) :6424-6432

[8] PHASE-DIAGRAM OF LIXC6 [J].

DAHN, JR .

PHYSICAL REVIEW B, 1991, 44 (17) :9170-9177

[9] ELECTROCHEMICAL DECOMPOSITION OF PROPYLENE CARBONATE ON GRAPHITE [J].

DEY, AN ;

SULLIVAN, BP .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1970, 117 (02) :222-&

[10] EMPIRICAL PARAMETERS FOR DONOR AND ACCEPTOR PROPERTIES OF SOLVENTS [J].

GUTMANN, V .

ELECTROCHIMICA ACTA, 1976, 21 (09) :661-670

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