Selective acid-functionalized mesoporous silica catalyst for conversion of glycerol to monoglycerides: state of the art and future prospects

被引:15
作者
Hermida, Lilis [1 ,2 ]
Amani, Hadis [1 ]
Saeidi, Samrand [3 ,4 ]
Abdullah, Ahmad Zuhairi [1 ]
Mohamed, Abdul Rahman [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Nibong Tebal 14300, Penang, Malaysia
[2] Univ Lampung, Dept Chem Engn, Bandar Lampung 35145, Lampung, Indonesia
[3] AREEO, Res Inst Forests & Rangelands, Dept Wood & Paper Sci, Tehran, Iran
[4] Amirkabir Univ Technol, Tehran Polytech, Sch Chem Engn, 424 Hafez Ave, Tehran 15914, Iran
关键词
acid functionalization; mesoporous catalyst; reaction phenomena; selective esterification of monoglyceride; synthesis procedure; POST-SYNTHESIS ALUMINATION; FRIEDEL-CRAFTS ACYLATION; MOLECULAR-SIEVES; SULFATED ZIRCONIA; FATTY-ACIDS; LAURIC ACID; EFFICIENT CATALYST; OLEIC-ACID; ACTIVE-SITES; PORE-SIZE;
D O I
10.1515/revce-2016-0039
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The quest for efficient and selective catalysts for conversion of glycerol monoglyceride is critical for the development of reliable methods for its synthesis. Thus, various types of catalyst and methods of catalyst manufacturing for conversion of glycerol to monoglycerides have been investigated. Acid-functionalized mesoporous catalysts are emerging as highly efficient catalysts for conversion of glycerol into monoglyceride. The incorporation of acid components into different mesoporous silicas for this application is reviewed in this work. The superiority of mesostructure catalysts in comparison to microporous catalysts has been elucidated in terms of accessibility to active sites, pore diffusion, thermal stability of the catalyst and catalyst reusability. Recent direction of novel acid-functionalized mesoporous catalysts development for this application is also critically reviewed.
引用
收藏
页码:239 / 265
页数:27
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