Measuring Electrochemical Surface Area of Nanomaterials versus the Randles-Sevcik Equation

被引:109
作者
Paixao, Thiago R. L. C. [1 ,2 ]
机构
[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, SP, Brazil
[2] Inst Nacl Ciencia & Tecnol Bioanalit, BR-13084971 Campinas, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Randles-Sevcik equation; electrode surface area; electrocatalysis; nanomaterials; current enhancement; GOLD; ELECTRODES; BEHAVIOR;
D O I
10.1002/celc.202000633
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This Viewpoint article is to call the attention of the nanomaterials community to a standard error when using the Randles-Sevcik equation to calculate the electrode surface area, as this error is continuously reported in the literature and the idea is to complete the conversation about the critical discussion based on the duality of electrocatalytic performance of nanomaterials and surface area in order to understand the electrocatalytic effect of these materials and not to simply attribute the current enhancement on the basis of an increase in surface area.
引用
收藏
页码:3414 / 3415
页数:2
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