Degradation of a model epoxy resin by solvolysis routes

被引:78
作者
Oliveux, Geraldine [1 ]
Dandy, Luke O. [1 ]
Leeke, Gary A. [1 ]
机构
[1] Univ Birmingham, Sch Chem Engn, Birmingham B15 2TT, W Midlands, England
基金
英国工程与自然科学研究理事会;
关键词
Recycling; Composites; Epoxy; Solvolysis; FIBER-REINFORCED COMPOSITES; CARBON-FIBER; GLASS-FIBER; UNSATURATED POLYESTER; POLYMER COMPOSITES; RECOVERY; DECOMPOSITION; PYROLYSIS; HYDROLYSIS; ALCOHOLS;
D O I
10.1016/j.polymdegradstab.2015.04.016
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Different technologies based on hydrolysis were applied to degrade an epoxy resin model: CO2-expanded water and generally recognised as safe solvents used neat or in mixture with water. The results showed that the degradation reaction can be enhanced thanks to the injection of CO2 or the addition of a solvent generally recognised as safe, enabling supercritical fluids or enhanced fluidity liquids (resembling supercritical fluids) at lower temperature and pressure than for supercritical water. (C) 2015 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license.
引用
收藏
页码:96 / 103
页数:8
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