β-cyclodextrin-cobalt ferrite nanocomposite as enhanced sensing platform for catechol determination

被引:31
作者
Han, Jin-Tu [1 ]
Huang, Ke-Jing [1 ]
Li, Jing [1 ]
Liu, Yan-Ming [1 ]
Yu, Meng [1 ]
机构
[1] Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
基金
中国国家自然科学基金;
关键词
Catechol; beta-cyclodextrin; Cobalt ferrite nanocomposite; Electrochemical sensor; PERFORMANCE LIQUID-CHROMATOGRAPHY; WALLED CARBON NANOTUBES; MODIFIED ELECTRODE; DIHYDROXYBENZENE ISOMERS; NANOPARTICLES; HYDROQUINONE; BIOSENSORS; FILM; PHENOL; HEMOGLOBIN;
D O I
10.1016/j.colsurfb.2012.05.003
中图分类号
Q6 [生物物理学];
学科分类号
071011 ;
摘要
An electrochemical sensor based on beta-cyclodextrin-cobalt ferrite nanocomposite was developed for the sensitive detection of catechol (CT). To construct the base of the sensor, a novel composite was initially fabricated and used as the substrate material by combining cobalt ferrite nanocomposite and beta-cyclodextrin via a simple sonication-induced assembly. Due to the high catechol-loading capacity on the electrode surface and the upstanding electric conductivity of cobalt ferrite nanocomposite, the electrochemical response of the fabricated sensor was greatly enhanced and displayed excellent analytical performance for catechol detection from 1 to 200 mu M with a low detection limit of 0.12 mu M (S/N = 3). Moreover, the developed electrochemical sensor exhibited good selectivity and acceptable reproducibility and could be used for the detection of catechol in water samples. (C) 2012 Elsevier By. All rights reserved.
引用
收藏
页码:58 / 62
页数:5
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