Ullmann Homocoupling Catalysed by Gold Nanoparticles in Water and Ionic Liquid

被引：48
|
作者：
Monopoli, Antonio [1 ]
Cotugno, Pietro
Palazzo, Gerardo
Ditaranto, Nicoletta
Mariano, Bruno
Cioffi, Nicola
Ciminale, Francesco
Nacci, Angelo [1 ]
机构：
[1] Univ Bari Aldo Moro, Dept Chem, CNR ICCOM, Via Orabona 4, I-70126 Bari, Italy
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 14-15期
关键词：
gold; ionic liquids; nanoparticles; Ullmann reaction; AEROBIC OXIDATION; PHENYLBORONIC ACID; HETEROGENEOUS CATALYSTS; ALKALINE-DEGRADATION; COUPLING REACTIONS; COMPLEXES; ALCOHOLS; GLUCOSE; SIZE; PHENYLACETYLENE;
D O I：
10.1002/adsc.201200422
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The gold-catalysed Ullmann-type homocoupling of aryl halides is carried out with two different methodologies: (i) under micellar catalysis conditions in water and (ii) using a molten tetralkylammonium ionic liquid as the reaction medium. Glucose is used as a clean and renewable reductant. Morphology, size, and chemical composition of the gold nanoparticles were ascertained by X-ray photoelectron spectroscopy, transmission electron microscopy and dynamic light scattering analyses. A plausible reaction mechanism is proposed.
引用
收藏
页码：2777 / 2788
页数：12
相关论文
共 50 条
  • [31] Antimicrobial Activity of Gold Nanoparticles and Ionic Gold
    Zhang, Ying
    Shareena Dasari, Thabitha P.
    Deng, Hua
    Yu, Hongtao
    JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART C-ENVIRONMENTAL CARCINOGENESIS & ECOTOXICOLOGY REVIEWS, 2015, 33 (03): : 286 - 327
  • [32] Interaction of water vapor with ionic liquid nanoparticles and thin films
    Nizkorodov, Sergey A.
    MacMillan, Amanda C.
    McIntire, Theresa M.
    Morrison, John W.
    Tobias, Douglas J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [33] Preparation of Zirconia Nanoparticles in Ionic Liquid-Water and Characterization
    Ma, Xiangdong
    Liu, Feilei
    Zhang, Hui
    Xu, Liu Jie
    Wei, Shizhong
    Li, Jiwen
    Zhang, Guoshang
    ADVANCES IN MECHANICAL ENGINEERING, PTS 1-3, 2011, 52-54 : 630 - +
  • [34] Preparation of albumin nanoparticles in water-in-ionic liquid microemulsions
    Demirkurt, Begum
    Cakan-Akdogan, Gulcin
    Akdogan, Yasar
    JOURNAL OF MOLECULAR LIQUIDS, 2019, 295
  • [35] Palladium-Nanoparticle-Catalysed Ullmann Reactions in Ionic Liquids with Aldehydes as the Reductants: Scope and Mechanism
    Calo, Vincenzo
    Nacci, Angelo
    Monopoli, Antonio
    Cotugno, Pietro
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (05) : 1272 - 1279
  • [36] Gold nanoparticles optical properties induced by water and an ionic liquid (bmimBF4) inside cationic reverse micelles
    Blach, Diana
    Martinez, Fernando O.
    NEW JOURNAL OF CHEMISTRY, 2017, 41 (21) : 13104 - 13113
  • [37] Synthesis of Gold Nanoparticles Using Lamellar Liquid Crystal of Protic Ionic Liquids
    Li, Qiuhong
    Li, Aixiang
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (02) : 847 - 850
  • [38] Ionic liquid functionalized gold nanoparticles: Synthesis, rapid colorimetric detection of imidacloprid
    Zhang, Xiaoyan
    Sun, Zhongyue
    Cui, Zhimin
    Li, Haibing
    SENSORS AND ACTUATORS B-CHEMICAL, 2014, 191 : 313 - 319
  • [39] Effect of Gold Nanoparticles on Transport Properties of the Protic Ionic Liquid Propylammonium Nitrate
    Garcia-Garabal, Sandra
    Dominguez-Perez, Montserrat
    Cabeza, Oscar
    Arosa, Yago
    Miguel Varela, Luis
    Fernandez-Lopez, Cristina
    Perez-Juste, Jorge
    Pastoriza-Santos, Isabel
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (08): : 3028 - 3037
  • [40] Micelles of Polymeric Ionic Liquid Block Copolymer as Templates for Preparation of Gold Nanoparticles
    Li, Junbo
    Han, Chen
    Zhang, Shijie
    Wu, Wenlan
    Zhou, Huiyun
    Guo, Jinwu
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (04) : 1081 - 1085
12345