W0.42Fe0.58 alloy, instead of pure W and Fe, was used to substitute Co in LaNi3.70Co0.2Mn0.30Al0.15Cu0.65 alloy to improve the overall electrochemical properties with the decrement of the cost. Microstructures and electrochemical characteristics of LaNi3.70Co0.2-xMn0.30Al0.15Cu0.65(W0.42Fe0.58)(x) (x = 0-0.20) hydrogen storage alloys were characterized. X-ray diffraction patterns and backscattered electron images indicated that the pristine alloy was LaNi5 phase, while the alloys containing W0.42Fe0.58 were made of LaNi5 matrix phase and W phase. The relatived abundance of W phase increased with the increase in x value. Lattice parameters a, c, c/ a and cell volume V of LaNi5 phase increased with increasing x value. Activation property of the alloy electrodes was improved by substituting Co by W0.42Fe0.58. As x increased from 0 to 0.20, maximum discharge capacity of alloy electrodes decreased from 335.4 (x = 0) to 320.7 mAh/ g (x= 0.20). The high-rate dischargeability at the discharge current density of 1200 mA increased from 59.8% (x = 0) to 76.8% (x = 0.10), and then decreased to 64.7% (x = 0.20). The cycling capacity retention rate at the 100th cycle decreased from 80.4% (x = 0) to 55.8% (x = 0.20), which should be ascribed to the degradation of the corrosion resistance and electrochemical kinetics of alloy electrodes.
