Charge-separated excited states in platinum(II) chromophores: Photophysics, formation, stabilization and utilization in solar energy conversion

被引：77
作者：
Archer, Stuart [1 ]
Weinstein, Julia A. [1 ]
机构：
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
来源：
COORDINATION CHEMISTRY REVIEWS | 2012年 / 256卷 / 21-22期
基金：
英国工程与自然科学研究理事会;
关键词：
Photoinduced charge separation; Pt(II) chromophores; Cascade electron transfer; Platinum(II) thiolates; Platinum(II) acetylides; Platinum(II) catecholates; Ultrafast spectroscopy; Time-resolved infrared spectroscopy; Time-resolved electronic spectroscopy; Vibrational relaxation; Artificial photosynthesis; Hydrogen production; DSSC; PHOTOINDUCED ELECTRON-TRANSFER; ROOM-TEMPERATURE PHOSPHORESCENCE; TRANSITION-METAL-COMPLEXES; ARTIFICIAL PHOTOSYNTHESIS; ACETYLIDE COMPLEXES; HYDROGEN-PRODUCTION; DIIMINE COMPLEXES; TRIPLET-STATE; RUTHENIUM PHOTOSENSITIZER; FEMTOSECOND FLUORESCENCE;
D O I：
10.1016/j.ccr.2012.07.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review discusses photophysical properties and application of diverse and broadly tuneable Pt(II) based chromophoric systems for solar energy conversion. Firstly, we outline photophysical properties of the prevailing classes of Pt(II) compounds, as classified by the donor ligand(s). A brief review of the multicomponent electron transfer cascade systems follows. The trends in the photophysical properties the lifetime of the charge-separated state, emission yields, etc. - as a function of the electronic and steric properties of the ligands are analysed. The final part considers emerging exciting applications of Pt(II) compounds in dye-sensitized solar cells and dihydrogen production. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：2530 / 2561
页数：32
相关论文
共 195 条
  • [51] Photocatalytic generation of hydrogen from water using a platinum(II) terpyridyl acetylide chromophore
    Du, Pingwu
    Schneider, Jacob
    Jarosz, Paul
    Eisenberg, Richard
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (24) : 7726 - 7727
  • [52] Rethinking Water Splitting
    Eisenberg, Richard
    [J]. SCIENCE, 2009, 324 (5923) : 44 - 45
  • [53] Bio-inspired, side-on attachment of a ruthenium photosensitizer to an iron hydrogenase active site model
    Ekstoem, Jesper
    Abrahamsson, Maria
    Olson, Carol
    Bergquist, Jonas
    Kaynak, Filiz B.
    Eriksson, Lars
    Licheng, Sun
    Becker, Hans-Christian
    Akermark, Bjoern
    Hammarstroem, Leif
    Ott, Sascha
    [J]. DALTON TRANSACTIONS, 2006, (38) : 4599 - 4606
  • [54] ELSAESSER T, 1991, ANNU REV PHYS CHEM, V42, P83
  • [55] Hydrogen production by molecular photocatalysis
    Esswein, Arthur J.
    Nocera, Daniel G.
    [J]. CHEMICAL REVIEWS, 2007, 107 (10) : 4022 - 4047
  • [56] Light-induced charge separation in ruthenium based triads -: New variations on an old theme
    Falkenstrom, Magnus
    Johansson, Olof
    Hammarstrom, Leif
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (03) : 741 - 750
  • [57] Photophysics of diplatinum polyynediyl oligomers: Chain length dependence of the triplet state in sp carbon chains
    Farley, Richard T.
    Zheng, Qinglin
    Gladysz, John A.
    Schanze, Kirk S.
    [J]. INORGANIC CHEMISTRY, 2008, 47 (08) : 2955 - 2963
  • [58] Architecture of the photosynthetic oxygen-evolving center
    Ferreira, KN
    Iverson, TM
    Maghlaoui, K
    Barber, J
    Iwata, S
    [J]. SCIENCE, 2004, 303 (5665) : 1831 - 1838
  • [59] Cobaloxime-based photocatalytic devices for hydrogen production
    Fihri, Aziz
    Artero, Vincent
    Razavet, Mathieu
    Baffert, Carole
    Leibl, Winfried
    Fontecave, Marc
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) : 564 - 567
  • [60] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE BY USING MACROCYCLES OF NICKEL AND COBALT
    FISHER, B
    EISENBERG, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (24) : 7361 - 7363
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