Synthesis, Structure and Thermal Properties of Bifurazano[3,4-b:3′,4′-f]furoxano[3",4"-d]oxacyclohetpatriene (BFFO)

被引：16
|
作者：
Zhou, Yanshui [2 ]
Xu, Kangzhen [1 ]
Wang, Bozhou [2 ]
Zhang, Hang [1 ]
Qiu, Qianqian [1 ]
Zhao, Fengqi [2 ]
机构：
[1] NW Univ Xian, Dept Chem Engn, Xian 710069, Peoples R China
[2] Xian Modern Chem Res Inst, Xian 710065, Peoples R China
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2012年 / 33卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Bifurazano[3,4-b:3 ',4 '-f]furoxano[3 '',4 ''-d]oxacyclohetpatriene (BFFO); Furazan; Crystal structure; Thermal properties; DECOMPOSITION; MACROCYCLES;
D O I：
10.5012/bkcs.2012.33.10.3317
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel energetic compound, bifurazano[3,4-b:3',4'-f]furoxano[3 '',4 ''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of BFFO center dot H2O is monoclinic, space group P2(1)/c with crystal parameters of a = 9.324(4) angstrom, b = 9.727(4) angstrom, c = 10.391(4) angstrom, beta = 106.305(6)degrees, V = 904.5(6) angstrom(3), Z = 4, mu = 0.17 mm(-1), F(000) = 512 and D-c = 1.866 g cm(-3). Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties.
引用
收藏
页码：3317 / 3320
页数：4
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