Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

被引：85

作者：

Fan, Lulu ^{[1
]}

Jia, Jiaqi ^{[1
]}

Hou, Hong ^{[1
]}

Lefebvre, Quentin ^{[1
]}

Rueping, Magnus ^{[1
,2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany

[2] KAUST, KAUST Catalysis Ctr KCC, Thuwal 239556900, Saudi Arabia

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 46期

基金：

欧洲研究理事会;

关键词：

amino acids; cross-coupling; decarboxylation; nickel catalysis; photoredox catalysis; SINGLE-ELECTRON TRANSMETALATION; VISIBLE-LIGHT PHOTOCATALYSIS; O BOND ACTIVATION; C-H BONDS; DUAL CATALYSIS; MERGING PHOTOREDOX; PHENOL DERIVATIVES; ORGANIC-SYNTHESIS; CARBOXYLIC-ACIDS; METAL CATALYSIS;

D O I：

10.1002/chem.201604452

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C-O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.

引用

页码：16437 / 16440

页数：4

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