Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

被引：84
|
作者：
Fan, Lulu [1 ]
Jia, Jiaqi [1 ]
Hou, Hong [1 ]
Lefebvre, Quentin [1 ]
Rueping, Magnus [1 ,2 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany
[2] KAUST, KAUST Catalysis Ctr KCC, Thuwal 239556900, Saudi Arabia
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 46期
基金：
欧洲研究理事会;
关键词：
amino acids; cross-coupling; decarboxylation; nickel catalysis; photoredox catalysis; SINGLE-ELECTRON TRANSMETALATION; VISIBLE-LIGHT PHOTOCATALYSIS; O BOND ACTIVATION; C-H BONDS; DUAL CATALYSIS; MERGING PHOTOREDOX; PHENOL DERIVATIVES; ORGANIC-SYNTHESIS; CARBOXYLIC-ACIDS; METAL CATALYSIS;
D O I：
10.1002/chem.201604452
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C-O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.
引用
收藏
页码：16437 / 16440
页数：4
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