3D printing of free-standing and flexible nitrogen doped graphene/polyaniline electrode for electrochemical energy storage

被引:19
作者
Zhou, Fuguo [1 ]
Han, Sancan [1 ]
Qian, Qingren [1 ]
Zhu, Yufang [1 ]
机构
[1] Univ Shanghai Sci & Technol, Sch Mat Sci & Engn, 516 Jungong Rd, Shanghai 200093, Peoples R China
基金
中国国家自然科学基金;
关键词
3D printing; Graphene; Flexible film; Polyaniline; Electrodeposition; GRAPHENE OXIDE; SUPERCAPACITORS; FABRICATION;
D O I
10.1016/j.cplett.2019.04.062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Flexible graphene film can be quickly realized by three-dimensional printing (3D printing), which has the potential in functional electronic devices. With a trace of cobalt ions as crosslinker, the graphene oxide sol can be converted into 3D printed ink, overcoming the disadvantage of insufficient viscosity of pure graphene oxide ink. The various graphene architectures were successfully obtained by 3D printing, moreover, graphene/polyaniline composites were obtained by electropolymerization. The specific capacitance of graphene/polyaniline electrode achieved up to 238 F/g at the current density of 0.5 A/g, which was much higher than that of graphene electrode (35 F/g).
引用
收藏
页码:6 / 13
页数:8
相关论文
共 38 条
[21]   Electronic materials - Buckling down for flexible electronics [J].
Lu, Xianmao ;
Xia, Younan .
NATURE NANOTECHNOLOGY, 2006, 1 (03) :163-164
[22]   Electric field effect in atomically thin carbon films [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Zhang, Y ;
Dubonos, SV ;
Grigorieva, IV ;
Firsov, AA .
SCIENCE, 2004, 306 (5696) :666-669
[23]   In Situ Growth of Layered Bimetallic ZnCo Hydroxide Nanosheets for High-Performance All-Solid-State Pseudocapacitor [J].
Pan, Zhichang ;
Jiang, Yingchang ;
Yang, Peiyu ;
Wu, Zeyi ;
Tian, Wenchao ;
Liu, Liu ;
Song, Yun ;
Gu, Qinfen ;
Sun, Dalin ;
Hu, Linfeng .
ACS NANO, 2018, 12 (03) :2968-2979
[24]   Solid-state microwave irradiation synthesis of high quality graphene nanosheets under hydrogen containing atmosphere [J].
Park, Sang-Hoon ;
Bak, Seong-Min ;
Kim, Kwang-Heon ;
Jegal, Jong-Pil ;
Lee, Sang-Ick ;
Lee, Jaeho ;
Kim, Kwang-Bum .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (03) :680-686
[25]   A X-ray diffraction analysis on graphene layers of Assam coal [J].
Saikia, Binoy K. ;
Boruah, Rajani K. ;
Gogoi, Pradip K. .
JOURNAL OF CHEMICAL SCIENCES, 2009, 121 (01) :103-106
[26]   Gravure Printing of Graphene for Large-Area Flexible Electronics [J].
Secor, Ethan B. ;
Lim, Sooman ;
Zhang, Heng ;
Frisbie, C. Daniel ;
Francis, Lorraine F. ;
Hersam, Mark C. .
ADVANCED MATERIALS, 2014, 26 (26) :4533-+
[27]   Fabrication of Graphene/Polyaniline Composite Paper via In Situ Anodic Electropolymerization for High-Performance Flexible Electrode [J].
Wang, Da-Wei ;
Li, Feng ;
Zhao, Jinping ;
Ren, Wencai ;
Chen, Zhi-Gang ;
Tan, Jun ;
Wu, Zhong-Shuai ;
Gentle, Ian ;
Lu, Gao Qing ;
Cheng, Hui-Ming .
ACS NANO, 2009, 3 (07) :1745-1752
[28]   Graphene-based in-plane micro-supercapacitors with high power and energy densities [J].
Wu, Zhong-Shuai ;
Parvez, Khaled ;
Feng, Xinliang ;
Muellen, Klaus .
NATURE COMMUNICATIONS, 2013, 4
[29]   Photolithographic fabrication of high-performance all-solid-state graphene-based planar micro-supercapacitors with different interdigital fingers [J].
Wu, Zhong-Shuai ;
Parvez, Khaled ;
Feng, Xinliang ;
Muellen, Klaus .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (22) :8288-8293
[30]   Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Graphene Oxide Sheets with Synergistic Effect for Energy Storage [J].
Xu, Jingjing ;
Wang, Kai ;
Zu, Sheng-Zhen ;
Han, Bao-Hang ;
Wei, Zhixiang .
ACS NANO, 2010, 4 (09) :5019-5026