Epitaxial Growth and Electronic Properties of Large Hexagonal Graphene Domains on Cu(111) Thin Film

被引:97
作者
Ago, Hiroki [1 ,2 ]
Kawahara, Kenji [1 ]
Ogawa, Yui [2 ]
Tanoue, Shota [2 ]
Bissett, Mark A. [1 ]
Tsuji, Masaharu [1 ,2 ]
Sakaguchi, Hidetsugu [2 ]
Koch, Roland J. [3 ]
Fromm, Felix [3 ]
Seyller, Thomas [3 ]
Komatsu, Katsuyoshi [4 ]
Tsukagoshi, Kazuhito [4 ]
机构
[1] Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan
[2] Kyushu Univ, Grad Sch Engn Sci, Fukuoka 8168580, Japan
[3] Tech Univ Chemnitz, Inst Phys, D-09126 Chemnitz, Germany
[4] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, Tsukuba, Ibaraki 3050044, Japan
关键词
CHEMICAL-VAPOR-DEPOSITION; SINGLE-LAYER GRAPHENE; LARGE-AREA; GRAIN-BOUNDARIES; CRYSTAL GRAPHENE; COPPER FOILS; HIGH-QUALITY; TRANSPORT; MOBILITY;
D O I
10.7567/APEX.6.075101
中图分类号
O59 [应用物理学];
学科分类号
摘要
Large hexagonal single-crystalline domains of single-layer graphene are epitaxially grown by ambient-pressure chemical vapor deposition over a thin Cu(111) film deposited on c-plane sapphire. The hexagonal graphene domains with a maximum size of 100 mu m are oriented in the same direction due to the epitaxial growth. Reflecting high crystallinity, a clear band structure with the Dirac cone is observed by angle-resolved photoelectron spectroscopy (ARPES), and a high carrier mobility exceeding 4,000 cm(2) V-1 s(-1) is obtained on SiO2/Si at room temperature. Our epitaxial approach combined with large domain growth is expected to contribute to future electronic applications. (C) 2013 The Japan Society of Applied Physics
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页数:4
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