Improvement of the glass-forming ability of Zr55Cu30Al10Ni5 and Cu47Ti34Zr11Ni83Ni8 alloys by electro-deoxidation of the melts

被引：24

作者：

Castellero, A.

Bossuyt, S.

Stoica, M.

Deledda, S.

Eckert, J.

Chen, G. Z.

Fray, D. J.

Greer, A. L.

机构：

[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

[2] IFW Dresden, Inst Met Mat, D-01171 Dresden, Germany

来源：

SCRIPTA MATERIALIA | 2006年 / 55卷 / 01期

关键词：

electro-deoxidation; liquid metal; casting; bulk amorphous materials;

D O I：

10.1016/j.scriptamat.2006.03.032

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A novel electrochemical method is presented for removing oxygen from glass-forming liquids in a molten-salt electrolyte. The effect of the electrolysis time on the glass-forming ability of Zr55Cu30Al10Ni5 and Cu47Ti34Zr11Ni8 was evaluated. Differential scanning calorimetry traces clearly show a stabilization of the amorphous phase as the electrolysis is performed for longer times, consistent with the hypothesis that the removal of oxygen from the melt improves its glass-forming ability. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

引用

页码：87 / 90

页数：4

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