Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II)

被引:2
作者
Zhao, Hong-Ying [2 ]
Song, Lian-Qing [3 ]
Wang, Jing-Wu [2 ]
Ng, Seik Weng [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
[3] Henan Inst Chem, Dept Chem, Zhengzhou 450014, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S160053680803907X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The complete molecule of the title compound, [CdFe2(C5H5)(2)(C12H8O2)(2)(CH4O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol molecules and by the O atoms of the two carboxylate anions (the latter in cis geometry), resulting in a distorted CdO6 octahedron. The phenylene ring is almost coplanar with its adjacent cyclopentadienyl ring [dihedral angle = 8.2 (2)degrees]. The uncoordinated carboxylate O atom acts as acceptor to two O-H center dot center dot center dot O hydrogen bonds from the methanol molecules, giving rise to a layered network.
引用
收藏
页码:M1624 / U1330
页数:12
相关论文
共 6 条
[1]  
Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189
[2]  
*BRUKER AXS INC, 2007, APEX2 SAINT
[3]   Novel one-dimensional polymers generated from p-ferrocenylbenzoate:: Syntheses, structures, and magnetic properties [J].
Hou, HW ;
Li, LK ;
Zhu, Y ;
Fan, YT ;
Qiao, YQ .
INORGANIC CHEMISTRY, 2004, 43 (15) :4767-4774
[4]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[5]  
SHELDRICK GM, 1996, SADAMS
[6]  
WESTRIP SP, 2008, PUBLCIF UNPUB