Optical and electrical characteristics of Ag-doped perylene diimide derivative

被引:21
作者
Chiu, Tien-Lung [1 ,2 ]
Xu, Wei-Feng [1 ,2 ]
Lin, Chi-Feng [1 ,2 ]
Lee, Jiun-Haw [1 ,2 ]
Chao, Chun-Chieh [3 ,4 ]
Leung, Man-Kit [3 ,4 ]
机构
[1] Natl Taiwan Univ, Dept Elect Engn, Taipei 10617, Taiwan
[2] Natl Taiwan Univ, Grad Inst Photon & Optoelect, Taipei 10617, Taiwan
[3] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
[4] Natl Taiwan Univ, Inst Polymer Sci & Engn, Taipei 10617, Taiwan
关键词
doping; electrical conductivity; nanoparticles; organic compounds; photoluminescence; silver; surface plasmons; thin films; visible spectra; SOLAR-CELLS; EFFICIENT; HETEROJUNCTIONS; PHOTODETECTORS; NANOPARTICLES; ABSORPTION; MIXTURES; POLYMER; CATHODE; DIODES;
D O I
10.1063/1.3068493
中图分类号
O59 [应用物理学];
学科分类号
摘要
In this paper, a highly conductive and strongly absorptive organic thin film by doping Ag into N,N(')-bis (2,6-di-isopropylphenyl)-1,7-bis (4-methoxy-phenyl) perylene-3,4,9,10-tetracarboxydiimide (MPPDI) was demonstrated. Strong absorption resulted from the broadband absorption of MPPDI at visible range and plasmon-enhanced absorption around 420 nm of Ag nanoparticles. Ag dopants in MPPDI acted as quenchers, which resulted in a dramatic decrease in photoluminescence intensity of MPPDI. Besides, J-V characteristics of Ag:MPPDI thin film changed from trapped-charge-limited current to Ohmic conduction with increasing Ag concentrations. Conductivity of 1.15x10(-6) Omega cm was achieved when MPPDI/Ag=5:1. This organic thin film has potential applications for low-reflectance organic light-emitting diode and organic photovoltaic device.
引用
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页数:3
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