共 25 条
Optical and electrical characteristics of Ag-doped perylene diimide derivative
被引:21
作者:
Chiu, Tien-Lung
[1
,2
]
Xu, Wei-Feng
[1
,2
]
Lin, Chi-Feng
[1
,2
]
Lee, Jiun-Haw
[1
,2
]
Chao, Chun-Chieh
[3
,4
]
Leung, Man-Kit
[3
,4
]
机构:
[1] Natl Taiwan Univ, Dept Elect Engn, Taipei 10617, Taiwan
[2] Natl Taiwan Univ, Grad Inst Photon & Optoelect, Taipei 10617, Taiwan
[3] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
[4] Natl Taiwan Univ, Inst Polymer Sci & Engn, Taipei 10617, Taiwan
关键词:
doping;
electrical conductivity;
nanoparticles;
organic compounds;
photoluminescence;
silver;
surface plasmons;
thin films;
visible spectra;
SOLAR-CELLS;
EFFICIENT;
HETEROJUNCTIONS;
PHOTODETECTORS;
NANOPARTICLES;
ABSORPTION;
MIXTURES;
POLYMER;
CATHODE;
DIODES;
D O I:
10.1063/1.3068493
中图分类号:
O59 [应用物理学];
学科分类号:
摘要:
In this paper, a highly conductive and strongly absorptive organic thin film by doping Ag into N,N(')-bis (2,6-di-isopropylphenyl)-1,7-bis (4-methoxy-phenyl) perylene-3,4,9,10-tetracarboxydiimide (MPPDI) was demonstrated. Strong absorption resulted from the broadband absorption of MPPDI at visible range and plasmon-enhanced absorption around 420 nm of Ag nanoparticles. Ag dopants in MPPDI acted as quenchers, which resulted in a dramatic decrease in photoluminescence intensity of MPPDI. Besides, J-V characteristics of Ag:MPPDI thin film changed from trapped-charge-limited current to Ohmic conduction with increasing Ag concentrations. Conductivity of 1.15x10(-6) Omega cm was achieved when MPPDI/Ag=5:1. This organic thin film has potential applications for low-reflectance organic light-emitting diode and organic photovoltaic device.
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