Solid monolayers of heptane adsorbed to graphite from its liquid

被引：11

作者：

Castro, MA

Clarke, SM

Inaba, A ^{[1
]}

Arnold, T

Thomas, RK

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

[2] Inst Ciencia Mat Sevilla, Seville, Spain

[3] Cavendish Lab, Cambridge CB3 0HE, England

[4] Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1999年 / 60卷 / 8-9期

基金：

英国工程与自然科学研究理事会;

关键词：

interfaces; surfaces; neutron scattering; crystal structure; surface properties;

D O I：

10.1016/S0022-3697(99)00152-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adsorption at the interface between liquid n-heptane and a graphite substrate has been studied by incoherent elastic/quasielastic neutron scattering and coherent neutron diffraction, A solid monolayer of n-heptane persists above the bulk melting point (183 K) and melts at 206 K, which is in contrast to the fact that the monolayer adsorbed at submonolayer coverages melts at 151 K. The crystalline structure is significantly different between those two monolayers. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1495 / 1497

页数：3

共 8 条

[1] New scattering techniques to characterise the structure of solid monolayers adsorbed from condensed phases to solid substrates
Castro, M
Clarke, SM
Inaba, A
Thomas, RK
[J]. PHYSICA B, 1997, 241 : 1086 - 1088
[2] Crystalline monolayer of dodecanoic acid adsorbed on graphite from n-heptane solution
Castro, MA
Clarke, SM
Inaba, A
Dong, CC
Thomas, RK
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (05) : 777 - 781
[3] Solid monolayers adsorbed at the solid-liquid interface studied by incoherent elastic neutron scattering
Castro, MA
Clarke, SM
Inaba, A
Thomas, RK
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (44): : 8878 - 8882
[4] CLARKE SM, IN PRESS J THERMAL A
[5] DIFFUSION IN PARAFFIN HYDROCARBONS
DOUGLASS, DC
MCCALL, DW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1958, 62 (09) : 1102 - 1107
[6] SELECTIVE ADSORPTION AT GRAPHITE/HYDROCARBON INTERFACES
GROSZEK, AJ
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1970, 314 (1519): : 473 - &
[7] *I LAU LANG, NEUTR RES FAC ILL HI
[8] HIGH-RESOLUTION NEUTRON SPECTROMETER LAM-80ET AND ROTATIONAL TUNNELING IN 4-METHYLPYRIDINE N-OXIDE
IKEDA, S
WATANABE, N
INOUE, K
KIYANAGI, Y
INABA, A
TAKEDA, S
KANAYA, T
SHIBATA, K
KAMIYAMA, T
IZUMI, Y
OZAKI, Y
CARLILE, CJ
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1991, 60 (10) : 3340 - 3350

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