Preparation and characterization of polylactide/poly(polyethylene glycol-co-citric acid) blends

被引：17

作者：

Gui, Zongyan ^{[1
]}

Xu, Yuanyuan ^{[1
]}

Cheng, Shujun ^{[1
]}

Gao, Yun ^{[1
]}

Lu, Chong ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China

来源：

POLYMER BULLETIN | 2013年 / 70卷 / 01期

关键词：

Polylactide; Biodegradable; Toughen; Processibility; Thermal property; Mechanical property; BIODEGRADABLE POLYMER BLENDS; REACTIVE PROCESSING AGENT; MECHANICAL-PROPERTIES; POLY(LACTIC ACID); GLYCIDYL METHACRYLATE; MELTING BEHAVIOR; VISCOSITY RATIO; MORPHOLOGY; CRYSTALLIZATION; POLYLACTIDE;

D O I：

10.1007/s00289-012-0810-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The blends of polylactide (PLA) and poly(polyethylene glycol-co-citric acid) (PEGCA) were prepared by melt mixing in an internal mixer. The effects of PEGCA content on the processibility, morphological, thermal, mechanical properties as well as hydrophilicity of PLA/PEGCA blends are investigated by rheometer, scanning electron microscopy, differential scanning calorimetry, mechanical testing, and water contact measurements. During thermal processing, the presence of PEGCA delayed the melting of PLA and lowered the viscosities of the blends. PLA/PEGCA blends exhibited a phase-separated morphology. The sizes of the dispersed phase increased with increased PEGCA content. The glass transition temperature of PLA decreased with the addition of PEGCA. The crystallization behaviors of PLA and PEGCA in their blends were influenced by each other. Ductility and toughness of PLA were significantly improved by the presence of PEGCA. PEGCA also greatly improved the hydrophilicity of PLA significantly.

引用

页码：325 / 342

页数：18

共 50 条

[1] Preparation and characterization of polylactide/poly(polyethylene glycol-co-citric acid) blends
Zongyan Gui
Yuanyuan Xu
Shujun Cheng
Yun Gao
Chong Lu
Polymer Bulletin, 2013, 70 : 325 - 342
[2] Preparation and characterization of polyethylene glycol/poly(L-lactic acid) blends
Athanasoulia, Ioanna-Georgia
Tarantili, Petroula A.
PURE AND APPLIED CHEMISTRY, 2017, 89 (01) : 141 - 152
[3] Poly(lactic acid)/low density polyethylene polymer blends: preparation and characterization
Hamad, Kotiba
Kaseem, Mosab
Deri, Fawaz
ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2012, 7 : S310 - S316
[4] Characterization of polylactide/poly(ethylene glycol) blends via direct pyrolysis mass spectrometry
Ozdemir, Esra
Tincer, Teoman
Hacaloglu, Jale
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2016, 122 : 315 - 322
[5] Preparation and Characterization of Biodegradable Polylactide/Thermoplastic Polyurethane Elastomer Blends
Han, Juan-Juan
Huang, Han-Xiong
JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 120 (06) : 3217 - 3223
[6] Preparation and characterization of polylactide/thermoplastic konjac glucomannan blends
Xu, Changgang
Luo, Xuegang
Lin, Xiaoyan
Zhuo, Xiurong
Liang, Lili
POLYMER, 2009, 50 (15) : 3698 - 3705
[7] Thermal and Mechanical Properties of Blends of Polylactide and Poly(ethylene glycol-co-propylene glycol): Influence of Annealing
Ran, Xianghai
Jia, Zhiyuan
Han, Changyu
Yang, Yuming
Dong, Lisong
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (04) : 2050 - 2057
[8] Polylactide/poly(hydroxybutyrate-co-hydroxyvalerate) blends: Morphology and mechanical properties
Gerard, T.
Budtova, T.
Podshivalov, A.
Bronnikov, S.
EXPRESS POLYMER LETTERS, 2014, 8 (08): : 609 - 617
[9] Properties of linear poly(lactic acid)/polyethylene glycol blends
Sungsanit, K.
Kao, N.
Bhattacharya, S. N.
POLYMER ENGINEERING AND SCIENCE, 2012, 52 (01) : 108 - 116
[10] Polylactide/polyvinyl acetate blends containing different molecular weights of poly(ethylene glycol)
Cheng, Wenxi
Cao, Yuanhang
Miao, Wei
Zhang, Yongjian
Tian, Li
Lin, Haowei
Song, Weiqiang
Zhang, Yike
Wang, Tao
IRANIAN POLYMER JOURNAL, 2024, 33 (12) : 1689 - 1699

← 1 2 3 4 5 →