Synthetic Strategies for Free & Stable N-Heterocyclic Carbenes and Their Precursors

被引：9

作者：

Bhatia, Rohit ^{[1
]}

Gaur, Jitender ^{[1
,2
,3
]}

Jain, Shilpa ^{[2
,3
]}

Lal, Arun ^{[1
]}

Tripathi, Brijesh ^{[5
]}

Attri, Pankaj ^{[1
,4
]}

Kaushik, Narender Kumar ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Delhi 110007, India

[2] J&S Res & Innovat, New Delhi 110092, India

[3] CSIR, Natl Phys Lab, New Delhi 110012, India

[4] Kwangwoon Univ, Dept Electro Biophys, Plasma Biosci Res Center, Seoul, South Korea

[5] SVBP Univ Agr & Technol, Basmati Export Dev Fdn, Meerut 250110, Uttar Pradesh, India

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2013年 / 10卷 / 02期

关键词：

Cyclopropylidene derivatives; Diphenylimidazolium perchlorate; Imidazolium ion; N-Heterocyclic Carbene; Tschugajeff's carbene complex; TRANSITION-METAL-COMPLEXES; ALKYL AMINO CARBENES; PD-II COMPLEXES; IMIDAZOLIUM SALTS; PALLADIUM(II) COMPLEXES; ARYL CHLORIDES; INTRAMOLECULAR HYDROIMINIUMATION; BIS(N-HETEROCYCLIC CARBENE); COORDINATION CHEMISTRY; CATALYTIC APPLICATION;

D O I：

10.2174/1570193X11310020007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recently, chemical cross coupling reactions have emerged as a powerful tool in the hands of synthetic organic chemist to synthesize complicated organic scaffolds like drugs, natural products, optical devices and industrially important materials. Stable N-Heterocyclic Carbene (NHC) acts as an important catalyst system in various cross coupling reactions. This review describes various strategies used for the synthesis of free and stable NHCs. Historical developments made in the propagation of the idea of free and stable carbene have also keenly been illustrated in the introduction of this review.

引用

页码：180 / 197

页数：18

共 163 条

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