New poly-o-quinonemethacrylate and its dioxygen-active antimony-containing polymer

被引：15
作者：
Arsenyev, Maxim V. [1 ]
Shurygina, Margarita P. [1 ]
Poddel'sky, Andrey I. [1 ]
Druzhkov, Nikolay O. [1 ]
Chesnokov, Sergey A. [1 ]
Fukin, Georgy K. [1 ]
Cherkasov, Vladimir K. [1 ]
Abakumov, Gleb A. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
来源：
JOURNAL OF POLYMER RESEARCH | 2013年 / 20卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
o-quinone; Methacrylate; Radical olymerization; Metal-polymer complexes; Thin films; REVERSIBLE BINDING; COMPLEXES; PYROCATECHOL; HYDROQUINONE; REACTIVITY; OXIDATION;
D O I：
10.1007/s10965-013-0098-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
o-Benzoquinonemethacrylate QMet is prepared by the reaction between 3,6-di-tert-butyl-o-benzoquinone and monomethacrylic ethers of ethylene glycol. Free radical polymerization of this monomer allows to synthesize polyo- benzoquinones Poly-QMet with molecular weight depending on the polymerization method and concentration of initiator. Polymerization in solution leads to polymer with 22-30 o-benzoquinone fragments in polymeric chain whereas bulk polymerization results in polymer with 110-190 o-benzoquinone fragments in polymeric chain. These polymers can be used in the preparation of metal-containing polymeric catecholate complexes. Triphenylantimony(V) polycatecholate Poly-SbCatMet is prepared by two ways - oxidative addition of SbPh3 to poly-o-quinone and polymerization of monomeric triphenylantimony catecholate SbCatMet. This polymeric catecholate Poly-SbCatMet is able to the reversible absorption of molecular oxygen on air both in solution and in thin film with conversion about 50-65 % (by NMR-spectroscopy and UV-vis data).
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页数：9
相关论文
共 31 条
  • [1] Reversible binding of dioxygen by a non-transition-metal complex
    Abakumov, GA
    Poddel'sky, AI
    Grunova, EV
    Cherkasov, VK
    Fukin, GK
    Kurskii, YA
    Abakumova, LG
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (18) : 2767 - 2771
  • [2] [Anonymous], 1998, SADABS V 2 01 BRUKER
  • [3] [Anonymous], 1972, CHEM COMPANION
  • [4] [Anonymous], 2000, SAINTPLUS DAR RED CO
  • [5] IRON AND COBALT LACUNAR COMPLEXES AS DIOXYGEN CARRIERS
    BUSCH, DH
    ALCOCK, NW
    [J]. CHEMICAL REVIEWS, 1994, 94 (03) : 585 - 623
  • [6] VANADIUM PEROXIDE COMPLEXES
    BUTLER, A
    CLAGUE, MJ
    MEISTER, GE
    [J]. CHEMICAL REVIEWS, 1994, 94 (03) : 625 - 638
  • [7] Triphenylantimony(v) catecholates and o-amidophenolates:: Reversible binding of molecular oxygen
    Cherkasov, Vladimir K.
    Abakumov, Gleb A.
    Grunova, Ekaterina V.
    Poddel'sky, Andrey I.
    Fukin, Georgy K.
    Baranov, Evgenii V.
    Kurskii, Yury V.
    Abakumova, Ludmila G.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (14) : 3916 - 3927
  • [8] Molecular and crystalline structure of 2,2-di(phenyl-4-ol)propane dimethacrylate, 2,2-di(phenyl-4-ol)propane diacrylate, pyrocatechol diacrylate, and hydroquinone diacrylate: Reactivity in melts
    Chesnokov, S. A.
    Zakharina, M. Yu.
    Fukin, G. K.
    Mamysheva, O. N.
    Chechet, Yu. V.
    Abakumov, G. A.
    [J]. POLYMER SCIENCE SERIES A, 2009, 51 (09) : 991 - 1001
  • [9] Biomimetic anchor for surface-initiated polymerization from metal substrates
    Fan, XW
    Lin, LJ
    Dalsin, JL
    Messersmith, PB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (45) : 15843 - 15847
  • [10] Fontecilla-Camps JC, 2006, BIOORGANOMETALLICS B
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