Syntheses, Crystal Structures and Properties of Cobalt(II) and Nickel(II) Complexes Based on 5-Methyl-1H-pyrazole-3-carboxylic Acid Ligand

被引：1
作者：
Cheng Mei-Ling [1 ,2 ]
Wang Shen [1 ,2 ]
Tang Li-Zhi-Peng [1 ,2 ]
Liu Qi [1 ,2 ,3 ]
机构：
[1] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Jiangsu, Peoples R China
[2] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Jiangsu, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210023, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 32卷 / 08期
关键词：
cobalt(II); nickel(II); 5-methyl-1H-pyrazole-3-carboxylic acid; crystal structure; photoluminescence; magnetic properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMER SYNTHESIS; ELECTROCHEMICAL PERFORMANCE; LUMINESCENT PROPERTIES; MAGNETIC-PROPERTY; ADSORPTION; MANGANESE; CHAIN; ZN; CU;
D O I：
10.11862/CJIC.2016.184
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new 1D chain-typed coordination polymers, {[Co (HMPCA)(2) (4,4'-bpy)](2)center dot 5H(2)O} (1) and {[Ni(HMPCA)(2)(pyz)]center dot 5H(2)O}(n) (2) (H(2)MPCA=5-methyl-1H-pyrazole-3-carboxylic acid, 4,4'-bpy=4,4'-bipyridine, pyz=pyrazine), have been synthesized and characterized by elemental analysis, IR spectra, single crystal X-ray diffraction and thermogravimetric analysis: Complex 1 crystallizes in the orthorhombic system, space group Pccn, and 2 crystallizes in the monoclinic system, space group P2/c. In 1 and 2, metal ions are both located in an octahedral geometry, coordinated by two nitrogen atoms and two oxygen atoms from two HMPCA(-) anions, and linked by two nitrogen atoms from 4,4'-bpy ligands (1) and pyz ligands (2), respectively, forming a 1D chain typed coordination polymer. The thermal stability, luminescent properties and magnetic properties of them have also been investigated. CCDC: 1445391, 1; 1445392, 2.
引用
收藏
页码：1457 / 1466
页数：10
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