Corrosion inhibition of dibenzo [1,4,8,11] tetraaza [14] annulene nickel on steel in 1 M HCl

被引:29
作者
Zhao, Peng [1 ]
Zhong, Cheng [1 ]
Hunag, Lei [1 ]
Niu, Lihong [1 ]
Zhang, Fushi [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Key Lab Organ Photoelectrons & Mol Engn, Minist Educ, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
Acid inhibition; Steel; EIS; Potentiodynamic; XPS;
D O I
10.1016/j.corsci.2008.06.015
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Dibenzo [1,4,8,11] tetraaza [14] annulene nickel (TAA-Ni) has been synthesized and its inhibitive behavior on mild steel in 1 M HCl was firstly investigated by gravimetric, potentiodynamic and impedance method. The potentiodynamic curves indicate the TAA-Ni mainly acted as mixed type inhibitor on electrochemistry in acid media. The weight loss result indicates TAA-Ni is good inhibitor in acid solution with the temperature changing from 303 K to 333 K. The XPS experiment indicates the protonation of TAA-Ni and its chemical adsorption on steel surface. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2166 / 2171
页数:6
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