Allocating movable resources dynamically enables evacuation management agencies to improve evacuation system performance in both the spatial and temporal dimensions. This study proposes a mixed integer linear program (MILP) model to address the dynamic resource allocation problem for transportation evacuation planning on large-scale networks. The proposed model is built on the earliest arrival flow formulation that significantly reduces problem size. A set of binary variables, specifically, the beginning and the ending time of resource allocation at a location, enable a strong formulation with tight constraints. A solution algorithm is developed to solve for an optimal solution on large-scale network applications by adopting Benders decomposition. In this algorithm, the MILP model is decomposed into two sub-problems. The first sub-problem, called the restricted master problem, identifies a feasible dynamic resource allocation plan. The second sub-problem, called the auxiliary problem, models dynamic traffic assignment in the evacuation network given a resource allocation plan. A numerical study is performed on the Dallas-Fort Worth network. The results show that the Benders decomposition algorithm can solve an optimal solution efficiently on a large-scale network. (C) 2015 Elsevier Ltd. All rights reserved.