New methods of resolution and enrichment of enantiomeric excesses of 1,1'-bi-2-naphthol

被引：61
作者：
Periasamy, M
Venkatraman, L
Thomas, KRJ
机构：
[1] UNIV HYDERABAD,SCH CHEM,HYDERABAD 500046,ANDHRA PRADESH,INDIA
[2] INDIAN INST TECHNOL,REG SOPHISTICATED INSTRUMENTAT CTR,MADRAS 600036,TAMIL NADU,INDIA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1997年 / 62卷 / 13期
关键词：
D O I：
10.1021/jo961937e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Partial resolution of racemic 1,1'-bi-2-naphthol (1) was readily achieved to obtain enriched (scalemic) 1 using (S)-proline (2). The structure of the complex 3 formed between 1 (2 equiv) and (S)-proline (1 equiv) was characterized by an X-ray diffraction method. Enantiomeric excesses of the incompletely resolved 1 were enriched to obtain essentially pure (R)- and (S)-1 following a simple procedure using B(OH)(3) an TMEDA.
引用
收藏
页码：4302 / 4306
页数：5
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