Hydrothermal synthesis and crystal structure of a manganese(II) compound bridged by 2,6-dichlorobenzoic acid

被引：0

作者：

Zhang Chun-Hua ^{[1
]}

Tang Si-Ping ^{[1
]}

Chen Man-Sheng ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

Deng Yi-Fang ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 24卷 / 09期

关键词：

manganese complex; crystal structure; 2,6-dichlorobenzoic acid; hydrothermal synthesis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A dinuclear manganese(II) complex, [Mn-2(L-1)(2)(phen)(4)]center dot(ClO4)(2) (1), has been synthesized and structurally characterized (HL1=2,6-dichlorobenzoic acid, phen=1,10-phenanthroline). It crystallizes in triclinic system, space group P1 with a=1.1123(4) nm, b=1.378 2(4) nm, c=2.085 7(3) nm, alpha=93.768(2)degrees, beta=90.606(10)degrees, gamma=95.606(3)degrees, V=3.174 8(15) nm(3), Z=2, C62H38Cl6Mn2N8O12, M-r=1 409.58, D-c=1.475 g.cm(-3), mu=0.718 mm(-1), F(000)=1 428, R= 0.064 3, wR =0.138 3. In the crystal the manganese atom is six-coordinated by two oxygen atoms from two different 2,6-dichlorobenzolate molecules and four nitrogen atoms from two 1,10-phenanthroline molecules, completing an octahedral geometry.

引用

页码：1519 / 1522

页数：4

共 16 条

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