Highly sensitive acetone sensors based on flame-spray-made La2O3-doped SnO2 nanoparticulate thick films

被引:47
|
作者
Tammanoon, N. [1 ,2 ]
Wisitsoraat, A. [3 ,4 ,5 ]
Phokharatkul, D. [3 ,4 ]
Tuantranont, A. [3 ,6 ]
Phanichphant, S. [3 ]
Yordsri, V. [7 ]
Liewhiran, C. [1 ,3 ,8 ]
机构
[1] Chiang Mai Univ, Fac Sci, Dept Phys & Mat Sci, Chiang Mai 50200, Thailand
[2] Chiang Mai Univ, Grad Sch, Chiang Mai 50200, Thailand
[3] Chiang Mai Univ, Fac Sci, Mat Sci Res Ctr, Ctr Adv Mat Printed Elect & Sensors, Chiang Mai 50200, Thailand
[4] Natl Sci & Technol Dev Agcy, Natl Elect & Comp Technol Ctr, Carbon Based Devices & Nanoelect Lab, Pathum Thani 12120, Thailand
[5] Thammasat Univ, Sirindhorn Int Inst Technol, Dept Common & Grad Studies, Pathum Thani 12120, Thailand
[6] Natl Sci & Technol Dev Agcy, Natl Elect & Comp Technol Ctr, Thailand Organ & Printed Elect Innovat Ctr, Pathum Thani 12120, Thailand
[7] Natl Sci & Technol Dev Agcy, Natl Met & Mat Technol Ctr, Pathum Thani 12120, Thailand
[8] Chiang Mai Univ, Ctr Excellence Mat Sci & Technol, Chiang Mai 50200, Thailand
关键词
Flame spray pyrolysis; Acetone; SnO2; La2O3; doping; Gas sensor; GAS-SENSING PROPERTIES; OXIDE; NANORODS; SURFACE; FERRITES; LA2O3; ZNO;
D O I
10.1016/j.snb.2018.01.238
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In the present work, flame-spray-made La2O3-doped SnO2 nanoparticles with 0.1-2 wt% La contents were systematically studied for acetone detection. The particle and sensing film properties were characterized by X-ray diffraction, nitrogen adsorption, electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. The sensing films were tested towards 0.1-400 ppm acetone at operating temperatures ranging from 150 to 400 degrees C in dry air. Gas-sensing results demonstrated that the SnO2 sensing film with the optimal La content of 0.5 wt% exhibited a very high response of 3626 toward 400 ppm acetone with a short response time of 2.8 s at the optimal operating temperature of 350 degrees C. Moreover, the sensors displayed high acetone selectivity against SO2, H2S, NO2, C6H6, C7H8, C8H10 and CH2O. Therefore, the La2O3-doped SnO2 sensors are promising for sensitive and selective detections of acetone at low concentrations. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:245 / 262
页数:18
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