Spontaneous disproportionation of rhodium(I) bisoxazolinates to rhodium(II)

被引:19
作者
Willems, STH [1 ]
Russcher, JC [1 ]
Budzelaar, PHM [1 ]
de Bruin, B [1 ]
de Gelder, R [1 ]
Smits, JMM [1 ]
Gal, AW [1 ]
机构
[1] Univ Nijmegen, Dept Inorgan Chem, NL-6525 ED Nijmegen, Netherlands
关键词
D O I
10.1039/b110183h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[Rh-I(t-Bu-2-boxate)(C2H4)(2)] spontaneously disproportionates to the mononuclear [Rh-II(t-Bu-2-boxate)(2)], whereas [Rh-I(Ph-2-boxate)(C2H4)(2)] is stable against disproportionation.
引用
收藏
页码:148 / 149
页数:2
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