Surface energy and surface tension of condensed matter and the principle of minimum potential energy of systems (revised)

被引:9
作者
Marichev, Victor A. [1 ]
机构
[1] Russian Acad Sci, Inst Phys Chem, Moscow, Russia
关键词
Surface energy; Surface tension; Their mutual dynamic transformation; Principle of minimum potential energy; SHUTTLEWORTH EQUATION; INTERFACES; SOLIDS; LAYER;
D O I
10.1007/s10008-012-1832-2
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We consider the essence and relation of the surface energy and surface tension of condensed matter: which is which aEuro broken vertical bar and (most important question here)-when? For the first time, this consideration is based not on reversible thermodynamics but, as an approximation, on the Principle of Minimum Potential Energy, given two factors: (1) the time-dependent dynamic transformation of the potential energy of the system into the surface energy and into the surface tension (stress); (2) elasticity of structured surface layers of the liquids.
引用
收藏
页码:3675 / 3681
页数:7
相关论文
共 35 条
[1]  
[Anonymous], 1906, The Scientific Papers of J. Willard Gibbs
[2]  
Bard AJ, 2008, ELECTROCHEMICAL DICT, P43
[3]   SURFACE ENERGY OF SOLIDS [J].
BIKERMAN, JJ .
PHYSICA STATUS SOLIDI, 1965, 10 (01) :3-&
[4]   THE FUNDAMENTAL CONCEPTS CONCERNING SURFACE TENSION AND CAPILLARITY [J].
BROWN, RC .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1947, 59 (333) :429-448
[5]   Systemic structural modular generalization of the crystallography of bound water applied to study the mechanisms of processes in biosystems at the atomic and molecular level [J].
Bulienkov, N. A. .
CRYSTALLOGRAPHY REPORTS, 2011, 56 (04) :680-697
[6]   Role of the surface layer of aqueous subphase in the self-organization mechanism of metal sulfide textures under a Langmuir monolayer [J].
Bulienkov, N. A. ;
Zheligovskaya, E. A. ;
Klechkovskaya, V. V. ;
Ivakin, G. I. .
CRYSTALLOGRAPHY REPORTS, 2011, 56 (03) :517-525
[7]  
Bulienkov N.A., 2009, J STRUCT CHEM, V50, pS86
[8]   Response to the Reply by D. J. Bottomley et al. to the comments written by J. C. Eriksson and A. I. Rusanov entitled Additional remarks related with the discussion inaugurated by the article Incompatibility of the Shuttleworth equation with Hermann's mathematical structure of thermodynamics by D. J. Bottomley et al. [Surf. Sci. 603 (2009) 97] [J].
Eriksson, Jan Christer ;
Rusanov, Anatoly I. .
SURFACE SCIENCE, 2010, 604 (21-22) :2069-2071
[9]   Density functional theory of size-dependent surface tension of Lennard-Jones fluid droplets using a double well type Helmholtz free energy functional [J].
Ghosh, Satinath ;
Ghosh, Swapan K. .
JOURNAL OF CHEMICAL PHYSICS, 2011, 135 (12)
[10]  
Gokhshtein A. J., 1971, ELEKTROCHIMIA, V7, P3