Highly Stretchable and Mechanically Stable Transparent Electrode Based on Composite of Silver Nanowires and Polyurethane-Urea

被引:92
作者
Kim, Dong-Hwan [1 ]
Yu, Ki-Cheol [1 ]
Kim, Youngmin [1 ]
Kim, Jong-Woong [1 ]
机构
[1] Korea Elect Technol Inst, Display Components & Mat Res Ctr, Songnam 463816, South Korea
关键词
stretchable electrode; Ag nanowire; intense pulsed light; polyurethane-urea; transparent electrode; SURFACE MODIFICATION; ELASTIC CONDUCTORS; PDMS; PERFORMANCE; ELASTOMER; NETWORKS; PLASMA;
D O I
10.1021/acsami.5b04693
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Transparent electrodes based on conventional, indium tin oxide - (ITO) can hardly meet the requirements of future generations of stretchable electronic devices) including artificial skin's, stretehable displays, sensors, and actuators, because they cannot retain, high conductivity under substantial stretching and bending deformation. Here we suggest a new approach for fabricating highly Stretchable and transparent electrodes with, good stability in environments where they would be stretched repeatedly. We designed polyurethane urea (PUU); a urethane-based polymer, to enhance the adhesion between Ag nanowires (AgNWs) and poly(dimethylsiloxane) (PDMS). The adhesion could be further improved when irradiated by intense pulsed light (IPL). After delicate optimization of the layered AgNW/PUU/PDMS Structure, we fabricated a stretchable transparent electrode that could withstand 100 Cycles of 50% stretching-releasing, with exceptionally high stability and reversibility. This newly developed electrode is therefore expected to be directly applicable to a wide range of high-performance, low-cost, stretchable electronic devices.
引用
收藏
页码:15214 / 15222
页数:9
相关论文
共 28 条
[1]   Reversibly Stretchable Transparent Conductive Coatings of Spray-Deposited Silver Nanowires [J].
Akter, Tahmina ;
Kim, Woo Soo .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (04) :1855-1859
[2]   Highly Stretchable and Sensitive Strain Sensor Based on Silver Nanowire-Elastomer Nanocomposite [J].
Amjadi, Morteza ;
Pichitpajongkit, Aekachan ;
Lee, Sangjun ;
Ryu, Seunghwa ;
Park, Inkyu .
ACS NANO, 2014, 8 (05) :5154-5163
[3]   Hydrophilization and hydrophobic recovery of PDMS by oxygen plasma and chemical treatment - An SEM investigation [J].
Bodas, Dhananjay ;
Khan-Malek, Chantal .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 123 (01) :368-373
[4]   Transfer Printing Techniques for Materials Assembly and Micro/Nanodevice Fabrication [J].
Carlson, Andrew ;
Bowen, Audrey M. ;
Huang, Yonggang ;
Nuzzo, Ralph G. ;
Rogers, John A. .
ADVANCED MATERIALS, 2012, 24 (39) :5284-5318
[5]   Mechanically strong and stretchable polyurethane-urea supramolecular hydrogel using water as an additional in situ chain extender [J].
Deng, Chao ;
Cui, Yulin ;
Zhao, Tingting ;
Tan, Mei ;
Huang, He ;
Guo, Mingyu .
RSC ADVANCES, 2014, 4 (46) :24095-24102
[6]   Flexible and Stretchable Polymers with Embedded Magnetic Nanostructures [J].
Donolato, Marco ;
Tollan, Christopher ;
Maria Porro, Jose ;
Berger, Andreas ;
Vavassori, Paolo .
ADVANCED MATERIALS, 2013, 25 (04) :623-629
[7]   Stretchable Conductors Based on Silver Nanowires: Improved Performance through a Binary Network Design [J].
Ge, Jin ;
Yao, Hong-Bin ;
Wang, Xu ;
Ye, Yin-Dong ;
Wang, Jin-Long ;
Wu, Zhen-Yu ;
Liu, Jian-Wei ;
Fan, Feng-Jia ;
Gao, Huai-Ling ;
Zhang, Chuan-Lin ;
Yu, Shu-Hong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (06) :1654-1659
[8]   Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene, and Metallic Nanostructures [J].
Hecht, David S. ;
Hu, Liangbing ;
Irvin, Glen .
ADVANCED MATERIALS, 2011, 23 (13) :1482-1513
[9]   Metal nanogrids, nanowires, and nanofibers for transparent electrodes [J].
Hu, Liangbing ;
Wu, Hui ;
Cui, Yi .
MRS BULLETIN, 2011, 36 (10) :760-765
[10]   Intrinsically stretchable transparent electrodes based on silver-nanowire-crosslinked-polyacrylate composites [J].
Hu, Weili ;
Niu, Xiaofan ;
Li, Lu ;
Yun, Sungryul ;
Yu, Zhibin ;
Pei, Qibing .
NANOTECHNOLOGY, 2012, 23 (34)