Glasses in the system ZrF4-BaF2-BiF3: Thermal and spectroscopic properties

被引：9

作者：

Ignatieva, L. N. ^{[1
]}

Surovtsev, N. V. ^{[2
]}

Savchenko, N. N. ^{[1
]}

Adichtchev, Sv. ^{[2
]}

Merkulov, E. B. ^{[1
]}

Marchenko, Yu. V. ^{[1
]}

Zverev, G. A. ^{[1
]}

Bouznik, V. M. ^{[3
]}

机构：

[1] Inst Chem FEB RAS, Vladivostok, Russia

[2] Inst Automat & Electrometry SB RAS, Novosibirsk, Russia

[3] All Russian Sci Res Inst Aviat Mat, Moscow, Russia

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2015年 / 426卷

关键词：

Fluorozirconate glass; crystallization; IR-spectra; Raman spectra; Photoluminescence; OPTICAL-PROPERTIES; IONIC-CONDUCTIVITY; DOPED GLASS; NMR; MOBILITY; RAMAN; NA;

D O I：

10.1016/j.jnoncrysol.2015.06.016

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The glasses in the ZrF4-BiF3-BaF2 system with different content of bismuth trifluoride have been investigated. The trends of the decrease of glass transition and crystallization temperatures along with the increase of the BiF3 content in glass, the presence of more than one crystallization peak and composition of crystalline phases in glasses have been revealed. All the studied glasses of the fluorozirconate series have nanosized heterogeneities of virtually the same scale. The crystallization process depends on the bismuth trifluoride content in glass. The contribution of photoluminescence of bismuth with transition emission 540 nm was found for the glass doped with 1% Bi. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：7 / 12

页数：6

共 32 条

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