Glasses in the system ZrF4-BaF2-BiF3: Thermal and spectroscopic properties

被引:9
作者
Ignatieva, L. N. [1 ]
Surovtsev, N. V. [2 ]
Savchenko, N. N. [1 ]
Adichtchev, Sv. [2 ]
Merkulov, E. B. [1 ]
Marchenko, Yu. V. [1 ]
Zverev, G. A. [1 ]
Bouznik, V. M. [3 ]
机构
[1] Inst Chem FEB RAS, Vladivostok, Russia
[2] Inst Automat & Electrometry SB RAS, Novosibirsk, Russia
[3] All Russian Sci Res Inst Aviat Mat, Moscow, Russia
关键词
Fluorozirconate glass; crystallization; IR-spectra; Raman spectra; Photoluminescence; OPTICAL-PROPERTIES; IONIC-CONDUCTIVITY; DOPED GLASS; NMR; MOBILITY; RAMAN; NA;
D O I
10.1016/j.jnoncrysol.2015.06.016
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The glasses in the ZrF4-BiF3-BaF2 system with different content of bismuth trifluoride have been investigated. The trends of the decrease of glass transition and crystallization temperatures along with the increase of the BiF3 content in glass, the presence of more than one crystallization peak and composition of crystalline phases in glasses have been revealed. All the studied glasses of the fluorozirconate series have nanosized heterogeneities of virtually the same scale. The crystallization process depends on the bismuth trifluoride content in glass. The contribution of photoluminescence of bismuth with transition emission 540 nm was found for the glass doped with 1% Bi. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:7 / 12
页数:6
相关论文
共 32 条
[1]  
Aggarwal I.D., 1991, Fluoride Glass Fiber Optics
[2]   IONIC-CONDUCTIVITY AND F-19 NMR INVESTIGATIONS OF SOME SERIES OF ZRF4-BASED FLUORIDE GLASSES CONTAINING LAF3 OR YF3 [J].
BOBE, JM ;
SENEGAS, J ;
REAU, JM ;
POULAIN, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1993, 162 (1-2) :169-177
[3]  
Brekhovskikh M.N., 2009, J INORG MATER, V45, P638
[4]  
Dianov E.M., 1987, RUSS J HIGH PURITY S, V3, P10
[5]   Bi-doped glass optical fibers: Is it a new breakthrough in laser materials? [J].
Dianov, Evgeny M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2009, 355 (37-42) :1861-1864
[6]   Effect of rare earth impurities on fluorescent cooling in ZBLAN glass [J].
Goldner, P ;
Mortier, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 284 (1-3) :249-254
[7]   EVALUATION OF GLASS-FORMING TENDENCY BY MEANS OF DTA [J].
HRUBY, A .
CZECHOSLOVAK JOURNAL OF PHYSICS SECTION B, 1972, B 22 (11) :1187-&
[8]   The peculiarities of fluoride glass structure. Spectroscopic study [J].
Ignatieva, L. N. ;
Surovtsev, N. V. ;
Plotnichenko, V. G. ;
Koltachev, V. V. ;
Merkulov, E. B. ;
Polyshchuk, S. A. ;
Bouznik, V. M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (13-15) :1238-1242
[9]   Structure and optical properties of glasses in systems ZrF4-BiF3-BaF2-PbF2-LnF3 [J].
Ignatieva, L. N. ;
Surovtsev, N. V. ;
Merkulov, E. B. ;
Savchenko, N. N. ;
Adichtchev, S. V. ;
Marchenko, Yu. V. ;
Bouznik, V. M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2012, 358 (23) :3248-3254
[10]   Glasses in the system of MnNbOF5-BaF2-BiF3-ErF3 [J].
Ignatieva, L. N. ;
Surovtsev, N. V. ;
Savchenko, N. N. ;
Adichtchev, S. V. ;
Polyshchuk, S. A. ;
Marchenko, Yu. V. ;
Bouznik, V. M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2011, 357 (22-23) :3807-3812