Spectrophotometric study of the photoinduced transformation of 4a,4c-dihydrodibenzophenanthrene to trans-1,2-di-(2-naphthyl)ethylene:: The proof of the one-photon mechanism by the method of singular decomposition

被引：0

作者：

Razumov, VF ^{[1
]}

Kazakov, SP ^{[1
]}

Ryabenko, AA ^{[1
]}

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, Chernogolovka 142432, Moskovskaya Obl, Russia

来源：

OPTICS AND SPECTROSCOPY | 1999年 / 86卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

It is proved by the mathematical method of singular decomposition of absorption spectra of a solution containing a photostationary mixture of isomers of 1,2-di-(2-naphthyl)ethylene that upon irradiation of 4a,4b-dihydrodibenzophenanthrene into its long-wavelength absorption band, along with cis-isomer of 1,2-di(2-naphthyl)ethylene, trans-isomer is produced in the one-photon process. Quantum yields of the photoinduced opening of the cycle are measured for both channels of the reaction.

引用

页码：537 / 543

页数：7