Separation of multi-milligram quantities of gossypol enantiomers on polysaccharide-based stationary phases

被引：11
|
作者：
Cass, QB [1 ]
Oliveira, RV [1 ]
机构：
[1] Univ Fed Sao Carlos, Dept Quim, BR-13560905 Sao Carlos, SP, Brazil
来源：
JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES | 2002年 / 25卷 / 05期
基金：
巴西圣保罗研究基金会;
关键词：
D O I：
10.1081/JLC-120003038
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
A column (200 x 7 nun ID) of cellulose tris(3,5-dimethylphenylcarbamate) coated onto naked silica (Hypersil, particle size, 5 mum; pore size, 120 Angstrom) was used under reversed-phase condition with recycle to enantioresolve multi-milligrams quantities of gossypol enantiomers. The use of amylose derivatives and the investigation on the influence of the acidity of the supports used for the polysaccharide phases in the enantioresolution of gossypol is also discussed.
引用
收藏
页码：819 / 829
页数：11
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