Preparation and properties of organic-inorganic hybrid thin films containing polysilane segments from polysilane-methacrylate copolymers

被引:36
作者
Matsukawa, K
Fukui, S
Higashi, N
Niwa, M
Inoue, H
机构
[1] Osaka Municipal Tech Res Inst, Joto Ku, Osaka 5368553, Japan
[2] Doshisya Univ, Fac Engn, Dept Mol Sci & Technol, Kyoto 6100321, Japan
关键词
D O I
10.1246/cl.1999.1073
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photo-radical copolymerization of 3-methacryloxypropyltrimethoxysilane was carried out by using polymethylphenylsilane as a macro-photoinitiator to form polysilane-methacryloxypropyltrimethoxysilane copolymers. Organic inorganic hybrid thin films with highly dispersed polysilane segments were successfully prepared from the copolymers by a sol-gel method. Refractive index and surface morphology of the hybrid thin films were found to change by UV irradiation.
引用
收藏
页码:1073 / 1074
页数:2
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