Recent Developments in Cathode Materials for Na Ion Batteries

被引：70

作者：

Fang Yong-Jin ^{[1
]}

Chen Zhong-Xue ^{[2
]}

Ai Xin-Ping ^{[1
]}

Yang Han-Xi ^{[1
]}

Cao Yu-Liang ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

[2] Wuhan Univ, Sch Power & Mech Engn, Wuhan 430072, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 2017年 / 33卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Sodium ion battery; Cathode material; Development; Sodium storage reaction; Electrochemical reaction mechanism; CARBON-COATED NA3V2(PO4)(3); SODIUM VANADIUM FLUOROPHOSPHATE; POSITIVE-ELECTRODE MATERIAL; HIGH-PERFORMANCE CATHODE; HIGH-CAPACITY CATHODE; PRUSSIAN BLUE ANALOG; ELECTROCHEMICAL PROPERTIES; LOW-COST; PYROPHOSPHATE CATHODE; STRUCTURAL EVOLUTION;

D O I：

10.3866/PKU.WHXB201610111

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sodium ion batteries (SIBs) have attracted increasing attention for energy storage systems because of abundant and low cost sodium resources. However, the large ionic radius of sodium and its slow electrochemical kinetics are the main obstacles for the development of suitable electrodes for high-performance SIBs. The development of high-performance cathode materials is the key to improving the energy density of SIBs and facilitating their commercialization. Herein, we review the latest advances and progress of cathode materials for SIBs, including transition metal oxides, polyanions, ferrocyanides, organic materials and polymers, and amorphous materials. Additionally, we have summarized our previous works in this area, explore the relationship between structure and electrochemical performance, and discuss effective ways to improve the reversibility, working potential and structural stability of these cathode materials.

引用

页码：211 / 241

页数：31

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