Applications of Flow Microreactors in Electrosynthetic Processes

被引:303
作者
Atobe, Mahito [1 ]
Tateno, Hiroyuki [1 ]
Matsumura, Yoshimasa [2 ]
机构
[1] Yokohama Natl Univ, Dept Environm & Syst Sci, Hodogaya Ku, Tokiwadai 79-7, Yokohama, Kanagawa 2408501, Japan
[2] Yamagata Univ, Fac Engn, Dept Chem & Chem Engn, Jonan 4-3-16, Yonezawa, Yamagata 9928510, Japan
关键词
INTERDIGITATED BAND ELECTRODES; PARALLEL LAMINAR-FLOW; SUPPORTED PAIRED ELECTROSYNTHESIS; IN-SITU ELECTROGENERATION; CROSS-COUPLING REACTION; HIGH-YIELD REACTION; OF-THE-ART; ELECTROCHEMICAL MICROREACTOR; ELECTROORGANIC SYNTHESIS; FUEL-CELLS;
D O I
10.1021/acs.chemrev.7b00353
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The fundamental advantages and potential benefits of flow microreactor technology include extremely large surface-to-volume ratios, precise control over temperature and residence time, extremely fast molecular diffusion, and increased safety during reactive processes. These advantages and benefits can be applied to a wide range of electrosynthetic techniques, and so the integration of flow microreactors with electrosynthesis has received significant research interest from both academia and industry. This review presents an up-to-date overview of electrosynthetic processes in continuous-flow microreactors. In addition, the advantages of continuous-flow electrochemistry are discussed, along with a thorough comparison of microreactor-based processes and conventional batch reaction systems.
引用
收藏
页码:4541 / 4572
页数:32
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