Applications of Flow Microreactors in Electrosynthetic Processes

被引：317
作者：
Atobe, Mahito [1 ]
Tateno, Hiroyuki [1 ]
Matsumura, Yoshimasa [2 ]
机构：
[1] Yokohama Natl Univ, Dept Environm & Syst Sci, Hodogaya Ku, Tokiwadai 79-7, Yokohama, Kanagawa 2408501, Japan
[2] Yamagata Univ, Fac Engn, Dept Chem & Chem Engn, Jonan 4-3-16, Yonezawa, Yamagata 9928510, Japan
来源：
CHEMICAL REVIEWS | 2018年 / 118卷 / 09期
关键词：
INTERDIGITATED BAND ELECTRODES; PARALLEL LAMINAR-FLOW; SUPPORTED PAIRED ELECTROSYNTHESIS; IN-SITU ELECTROGENERATION; CROSS-COUPLING REACTION; HIGH-YIELD REACTION; OF-THE-ART; ELECTROCHEMICAL MICROREACTOR; ELECTROORGANIC SYNTHESIS; FUEL-CELLS;
D O I：
10.1021/acs.chemrev.7b00353
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The fundamental advantages and potential benefits of flow microreactor technology include extremely large surface-to-volume ratios, precise control over temperature and residence time, extremely fast molecular diffusion, and increased safety during reactive processes. These advantages and benefits can be applied to a wide range of electrosynthetic techniques, and so the integration of flow microreactors with electrosynthesis has received significant research interest from both academia and industry. This review presents an up-to-date overview of electrosynthetic processes in continuous-flow microreactors. In addition, the advantages of continuous-flow electrochemistry are discussed, along with a thorough comparison of microreactor-based processes and conventional batch reaction systems.
引用
收藏
页码：4541 / 4572
页数：32
相关论文
共 133 条
[11]   A thin-gap cell for selective oxidation of 4-methylanisole to 4-methoxy-benzaldehyde-dimethylacetal [J].
Attour, Anis ;
Rode, Sabine ;
Ziogas, Athanassios ;
Matlosz, Michael ;
Lapicque, Francois .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2008, 38 (03) :339-347
[12]  
Bard A.J., 2001, Electrochemical Methods: Fundamentals and Applications, P29
[13]   DIGITAL-SIMULATION OF THE MEASURED ELECTROCHEMICAL RESPONSE OF REVERSIBLE REDOX COUPLES AT MICROELECTRODE ARRAYS - CONSEQUENCES ARISING FROM CLOSELY SPACED ULTRAMICROELECTRODES [J].
BARD, AJ ;
CRAYSTON, JA ;
KITTLESEN, GP ;
SHEA, TV ;
WRIGHTON, MS .
ANALYTICAL CHEMISTRY, 1986, 58 (11) :2321-2331
[14]   DEVELOPMENT OF NEW CELLS FOR ELECTRO-ORGANIC SYNTHESES [J].
BECK, F ;
GUTHKE, H .
CHEMIE INGENIEUR TECHNIK, 1969, 41 (17) :943-&
[15]   Coplanar interdigitated band electrodes for electrosynthesis. Part 4: Application to sea water electrolysis [J].
Belmont, C ;
Ferrigno, R ;
Leclerc, O ;
Girault, HH .
ELECTROCHIMICA ACTA, 1998, 44 (04) :597-603
[16]   COPLANAR INTERDIGITATED BAND ELECTRODES FOR ELECTROSYNTHESIS .2. METHOXYLATION OF FURAN [J].
BELMONT, C ;
GIRAULT, HH .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1994, 24 (08) :719-724
[17]   COPLANAR INTERDIGITATED BAND ELECTRODES FOR ELECTROSYNTHESIS .3. EPOXIDATION OF PROPYLENE [J].
BELMONT, C ;
GIRAULT, HH .
ELECTROCHIMICA ACTA, 1995, 40 (15) :2505-2510
[18]   Chemical hydrides: A solution to high capacity hydrogen storage and supply [J].
Biniwale, Rajesh B. ;
Rayalu, S. ;
Devotta, S. ;
Ichikawa, M. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (01) :360-365
[19]   Microstructured reactor for electroorganic synthesis [J].
Bouzek, Karel ;
Jiricny, Vladimir ;
Kodym, Roman ;
Krist'al, Jiri ;
Bystron, Tomas .
ELECTROCHIMICA ACTA, 2010, 55 (27) :8172-8181
[20]   Miniaturized flow system based on enzyme modified PMMA microreactor for amperometric determination of glucose [J].
Cerdeira Ferreira, Luis Marcos ;
da Costa, Eric Tavares ;
do Lago, Claudimir Lucio ;
Angnes, Lucio .
BIOSENSORS & BIOELECTRONICS, 2013, 47 :539-544
12345678910