Liquid phase oxidation of alkenes with nitrous oxide to carbonyl compounds

被引：51

作者：

Starokon, EV ^{[1
]}

Dubkov, KA ^{[1
]}

Babushkin, DE ^{[1
]}

Parmon, VN ^{[1
]}

Panov, GI ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 2-3期

关键词：

alkenes oxidation; carbene; carbonyl compounds; cycloheptatriene; cyclopropane; methylene; nitrous oxide;

D O I：

10.1002/adsc.200303155

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A variety of substrates including linear, cyclic, heterocyclic alkenes and their derivatives were tested in the liquid phase non-catalytic oxidation with nitrous oxide (N2O). The structure and composition of the alkenes have a significant effect on the reaction selectivity. With many alkenes, N2O oxidation provides a selective way for the preparation of carbonyl compounds. The generation of carbene (or diazomethane) species is a remarkable feature of the oxidation of terminal alkenes.

引用

页码：268 / 274

页数：7

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