Liquid phase oxidation of alkenes with nitrous oxide to carbonyl compounds

被引：51
|
作者：
Starokon, EV [1 ]
Dubkov, KA [1 ]
Babushkin, DE [1 ]
Parmon, VN [1 ]
Panov, GI [1 ]
机构：
[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 2-3期
关键词：
alkenes oxidation; carbene; carbonyl compounds; cycloheptatriene; cyclopropane; methylene; nitrous oxide;
D O I：
10.1002/adsc.200303155
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A variety of substrates including linear, cyclic, heterocyclic alkenes and their derivatives were tested in the liquid phase non-catalytic oxidation with nitrous oxide (N2O). The structure and composition of the alkenes have a significant effect on the reaction selectivity. With many alkenes, N2O oxidation provides a selective way for the preparation of carbonyl compounds. The generation of carbene (or diazomethane) species is a remarkable feature of the oxidation of terminal alkenes.
引用
收藏
页码：268 / 274
页数：7
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