Predissociation rates in the B2 Sigma(-) state of CH

被引：10

作者：

Luque, J ^{[1
]}

Crosley, DR ^{[1
]}

机构：

[1] SRI INT,MOLEC PHYS LAB,MENLO PK,CA 94025

来源：

CHEMICAL PHYSICS | 1996年 / 206卷 / 1-2期

关键词：

D O I：

10.1016/0301-0104(95)00443-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rotationally dependent predissociation rates have been determined for the levels N' = 15-17 in v' = 0 and N' = 7, 8 in v' = 1 of the B-2 Sigma(-) state of the CH radical, from measured quantum yields of laser-induced fluorescence in a low pressure methane/oxygen flame. The lifetimes decrease very quickly with rotational quantum number and show good agreement with previous theoretical calculations.

引用

页码：185 / 192

页数：8

共 22 条

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