One-step Nanocasting Synthesis of Ordered Mesoporous Carbon with Graphitic Frameworks

被引:0
作者
Wang, Yangang [1 ]
Wang, Fei [1 ]
Chen, Yuting [1 ]
Li, Bo [2 ]
Zhang, Chengli [2 ]
Cui, Lifeng [1 ]
Kang, Shifei [2 ]
Li, Xi [2 ]
机构
[1] Shanghai Univ Sci & Technol, Dept Environm Sci & Engn, Shanghai 200093, Peoples R China
[2] Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2013年 / 8卷 / 06期
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
mesoporous carbon; graphitic frameworks; soybean oil; one-step nanocasting; HYDROGEN STORAGE; CARBONIZATION; PERFORMANCE; FABRICATION; ADSORPTION; TEMPLATES; CAPACITY; POLYMERS; ROUTE;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A simple one-step nanocasting route has been demonstrated to synthesize ordered mesoporous carbon with graphitic frameworks. In the synthesis, the complicated carbon precursor impregnation step is no longer used and the carbon precursor (soybean oil) is incorporated into the mesopore channels in the hydrophobic domain of the triblock copolymers due to the coordination function through the preparation the ordered mesoporous silica SBA-15. It was found that the as-prepared graphitic carbon material has an ordered 2D hexagonal mesostructure with a rod-like morphology, a high specific surface area (813.7 m(2) g(-1)) and a large pore volume (0.758 cm(3) g(-1)), giving the material wide potential applications as catalyst support, adsorbent and electrode material.
引用
收藏
页码:7868 / 7874
页数:7
相关论文
共 22 条
[1]   Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries [J].
Fan, J ;
Wang, T ;
Yu, CZ ;
Tu, B ;
Jiang, ZY ;
Zhao, DY .
ADVANCED MATERIALS, 2004, 16 (16) :1432-+
[2]   Fabrication of new nanoporous carbons through silica templates and their application to the adsorption of bulky dyes [J].
Han, SJ ;
Sohn, K ;
Hyeon, T .
CHEMISTRY OF MATERIALS, 2000, 12 (11) :3337-3341
[3]   Adsorption of vitamin E on mesoporous carbon molecular sieves [J].
Hartmann, M ;
Vinu, A ;
Chandrasekar, G .
CHEMISTRY OF MATERIALS, 2005, 17 (04) :829-833
[4]   High-performance direct methanol fuel cell electrodes using solid-phase-synthesized carbon nanocoils [J].
Hyeon, T ;
Han, S ;
Sung, YE ;
Park, KW ;
Kim, YW .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) :4352-4356
[5]   Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles [J].
Joo, SH ;
Choi, SJ ;
Oh, I ;
Kwak, J ;
Liu, Z ;
Terasaki, O ;
Ryoo, R .
NATURE, 2001, 412 (6843) :169-172
[6]   Toward new candidates for hydrogen storage: High-surface-area carbon aerogels [J].
Kabbour, Houria ;
Baumann, Theodore F. ;
Satcher, Joe H., Jr. ;
Saulnier, Angelique ;
Ahn, Channing C. .
CHEMISTRY OF MATERIALS, 2006, 18 (26) :6085-6087
[7]   Direct synthesis of uniform mesoporous carbons from the carbonization of as-synthesized silica/triblock copolymer nanocomposites [J].
Kim, J ;
Lee, J ;
Hyeon, T .
CARBON, 2004, 42 (12-13) :2711-2719
[8]   Nanocasting of carbon nanotubes:: in-situ graphitization of a low-cost mesostructured silica templated by non-ionic surfactant micelles [J].
Kim, SS ;
Lee, DK ;
Shah, J ;
Pinnavaia, TJ .
CHEMICAL COMMUNICATIONS, 2003, (12) :1436-1437
[9]   A synthetic route to ordered mesoporous carbon materials with graphitic pore walls [J].
Kim, TW ;
Park, IS ;
Ryoo, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) :4375-4379
[10]   Ordered mesoporous carbons from the carbonization of sulfuric-acid-treated silica/triblock copolymer/sucrose composites [J].
Li, Lixia ;
Song, Huaihe ;
Chen, Xiaohong .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 94 (1-3) :9-14