Enhanced ferroelectric properties of LiNbO3 substituted Na0.5K0.5NbO3 lead-free thin films grown by chemical solution deposition

被引:56
作者
Ahn, Chang Won [1 ]
Jeong, Euh Duck [1 ]
Lee, Sun Young [2 ]
Lee, Hai Joon [2 ]
Kang, Sun Hee [2 ]
Kim, Ill Won [2 ]
机构
[1] Korea Basic Sci Inst, High Technol Components & Mat Res Ctr, Pusan 618230, South Korea
[2] Univ Ulsan, Dept Phys, Ulsan 680749, South Korea
关键词
dielectric hysteresis; dielectric thin films; ferroelectric ceramics; ferroelectric Curie temperature; leakage currents; liquid phase deposition; lithium compounds; piezoceramics; potassium compounds; sodium compounds;
D O I
10.1063/1.3037214
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have fabricated environmental friendly lead-free ferroelectric Na0.5K0.5NbO3 (NKN) and 0.95Na(0.5)K(0.5)NbO(3)-0.05LiNbO(3) (0.95NKN-0.05LN) thin films by chemical solution deposition using metal-organic compounds, and studied the effects of LN substitution through the dielectric and ferroelectric properties. The small amount of LN substitution for NKN thin film led to a marked improvement in leakage current properties at the high electric field region. Furthermore, the 0.95NKN-0.05LN thin film (350 nm) displayed clear ferroelectricity with well saturated P-E hysteresis loop with 2P(r) and 2E(c) values of 19.5 mu C/cm(2) and 91 kV/cm, respectively. The 0.95NKN-0.05LN films will be interesting for applications in lead-free ferroelectric and piezoelectric devices.
引用
收藏
页数:3
相关论文
共 25 条
  • [21] Relaxor single crystals in the (Bi1/2Na1/2)1-xBaxZryTi1-yO3 system exhibiting high electrostrictive strain
    Sheets, SA
    Soukhojak, AN
    Ohashi, N
    Chiang, YM
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) : 5287 - 5295
  • [22] Piezoelectric properties of (K,Na)NbO3 films deposited by RF magnetron sputtering
    Shibata, Kenji
    Oka, Furnihito
    Ohishi, Akio
    Mishima, Tornoyoshi
    Kanno, Isaku
    [J]. APPLIED PHYSICS EXPRESS, 2008, 1 (01)
  • [23] Effect of (Na,K)-Excess precursor solutions on alkoxy-derived (Na,K)NbO3 powders and thin films
    Tanaka, Kiyotaka
    Hayashi, Hiromi
    Kakimoto, Ken-ichi
    Ohsato, Hitoshi
    Iijima, Takashi
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2007, 46 (10B): : 6964 - 6970
  • [24] Piezoelectric properties of spark-plasma-sintered (Na 0.5K0.5)NbO3-PbTiO3 ceramics
    Wang, RP
    Xie, RJ
    Sekiya, T
    Shimojo, Y
    Akimune, Y
    Hirosaki, N
    Itoh, M
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2002, 41 (11B): : 7119 - 7122
  • [25] Mitigation of thermal and fatigue behavior in K0.5Na0.5NbO3-based lead free piezoceramics
    Zhang, Shujun
    Xia, Ru
    Hao, Hua
    Liu, Hanxing
    Shrout, Thomas R.
    [J]. APPLIED PHYSICS LETTERS, 2008, 92 (15)