Controlling the crystalline structure of imine-linked 3D covalent organic frameworks

被引：47
|
作者：
Fischbach, Danyon M. [1 ]
Rhoades, Grace [1 ]
Espy, Charlie [1 ]
Goldberg, Fallon [1 ]
Smith, Brian J. [1 ]
机构：
[1] Bucknell Univ, Rooke Sci Ctr, Dept Chem, Lewisburg, PA 17837 USA
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 25期
关键词：
STORAGE; NETWORKS; PLATFORM;
D O I：
10.1039/c8cc09571j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We explore the growth mechanism of 3D Covalent Organic Frameworks (COFs) using imine-linked model systems. We confirm that 3D imine COFs crystalize through an amorphous polymer intermediate, whose conditional state is key for preferential generation of the ideal porous structure over the collapsed hydrated form.
引用
收藏
页码：3594 / 3597
页数：4
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