Controlling the crystalline structure of imine-linked 3D covalent organic frameworks

被引：47
|
作者：
Fischbach, Danyon M. [1 ]
Rhoades, Grace [1 ]
Espy, Charlie [1 ]
Goldberg, Fallon [1 ]
Smith, Brian J. [1 ]
机构：
[1] Bucknell Univ, Rooke Sci Ctr, Dept Chem, Lewisburg, PA 17837 USA
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 25期
关键词：
STORAGE; NETWORKS; PLATFORM;
D O I：
10.1039/c8cc09571j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We explore the growth mechanism of 3D Covalent Organic Frameworks (COFs) using imine-linked model systems. We confirm that 3D imine COFs crystalize through an amorphous polymer intermediate, whose conditional state is key for preferential generation of the ideal porous structure over the collapsed hydrated form.
引用
收藏
页码：3594 / 3597
页数：4
相关论文
共 50 条
  • [1] A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
    Uribe-Romo, Fernando J.
    Hunt, Joseph R.
    Furukawa, Hiroyasu
    Klock, Cornelius
    O'Keeffe, Michael
    Yaghi, Omar M.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (13) : 4570 - +
  • [2] Heterogeneous nucleation and growth of highly crystalline imine-linked covalent organic frameworks
    Yuan, Yu-Chen
    Sun, Bing
    Cao, An-Min
    Wang, Dong
    Wan, Li-Jun
    CHEMICAL COMMUNICATIONS, 2018, 54 (47) : 5976 - 5979
  • [3] Water splitting at imine-linked covalent organic frameworks
    Gottwald, Felizitas
    Penschke, Christopher
    Saalfrank, Peter
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2024, 26 (32) : 21821 - 21831
  • [4] Imine-linked covalent organic frameworks with controllable morphology
    Guo, Lijun
    Chen, Wei
    Li, Yang
    Wei, Zimeng
    Li, Feng
    Li, Cuiqin
    MATERIALS CHEMISTRY AND PHYSICS, 2023, 301
  • [5] Improved synthesis and applications of imine-linked covalent organic frameworks
    Dichtel, William
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [6] Functionalized modulators in imine-linked covalent organic frameworks (COFs)
    Dautzenberg, Ellen
    Claassen, Frank W.
    de Smet, Louis C. P. M.
    MICROPOROUS AND MESOPOROUS MATERIALS, 2023, 350
  • [7] Synthesis of highly crystalline imine-linked covalent organic frameworks via controlling monomer feeding rates in an open system
    Wang, Xueqing
    Liu, Manying
    Wang, Xiaoyan
    Tan, Bien
    CHEMICAL COMMUNICATIONS, 2022, 58 (88) : 12313 - 12316
  • [8] Imine-linked covalent organic frameworks coordinated with nickel for ethylene oligomerization
    Guo, Lijun
    Gao, Yuxin
    Huang, Jin
    Xue, Jingqi
    Li, Feng
    Li, Cuiqin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2023, 140 (03)
  • [9] Dynamic Imine Exchange Reactions for Facile Synthesis of Imine-Linked Covalent Organic Frameworks
    Wang, Xiao-Lian
    Zhang, Li-Tian
    He, Shan
    Chen, Xiao-Xian
    Huang, Xiao-Chun
    Zhou, Hao-Long
    CHEMISTRY OF MATERIALS, 2023, 35 (23) : 10070 - 10077
  • [10] Protonated Imine-Linked Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution
    Yang, Jin
    Acharjya, Amitava
    Ye, Meng-Yang
    Rabeah, Jabor
    Li, Shuang
    Kochovski, Zdravko
    Youk, Sol
    Roeser, Jerome
    Grueneberg, Julia
    Penschke, Christopher
    Schwarze, Michael
    Wang, Tianyi
    Lu, Yan
    van de Krol, Roel
    Oschatz, Martin
    Schomaecker, Reinhard
    Saalfrank, Peter
    Thomas, Arne
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (36) : 19797 - 19803
12345